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Merck
CN

M2284

乙酰丙酮锰(III)

technical grade

别名:

2,4-戊二酮 锰(III) 衍生物, 乙酰丙酮锰, 锰(acac)3

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关于此项目

线性分子式:
Mn(C5H7O2)3
化学文摘社编号:
分子量:
352.26
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
238-188-3
MDL number:
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InChI key

HYZQBNDRDQEWAN-LNTINUHCSA-K

InChI

1S/3C5H8O2.Mn/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

SMILES string

CC(=O)\C=C(\C)O[Mn](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

grade

technical grade

reaction suitability

core: manganese, reagent type: catalyst

Quality Level

Application

氧化剂用于氧化酚类,β-二羰基化合物和硫醇。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Nishino, H. Tategami, S. et al.
Bulletin of the Chemical Society of Japan, 64, 1800-1800 (1991)
Snider, B. B.; Patricia, J. J. et al.
The Journal of Organic Chemistry, 53, 2137-2137 (1988)
Gui-Ge Hou et al.
Chemical communications (Cambridge, England), 47(38), 10731-10733 (2011-08-27)
Two NbO-type MOFs based on ditopic pyridyl substituted diketonate ligands were reported. One exhibits a reversible SC-SC water encapsulation, while the other shows an interesting guest-driven luminescent property based on M(III) acetylacetonate (M = Eu and Fe) guest species.
Ik-Soo Shin et al.
The Analyst, 136(10), 2151-2155 (2011-03-25)
Though recently Ir(III) complexes have attracted much interest in electrochemiluminescent (ECL) analysis due to their high emission in various wavelengths, there were a few studies reported on its analytical applications. In this study, we evaluate the ECL from (pq)(2)Ir(acac) (pq
Chih-Chia Huang et al.
Chemical communications (Cambridge, England), (23)(23), 3360-3362 (2009-06-09)
A general approach involving a solvothermal method was developed to synthesize a series of silicate nanoshells (<100 nm) where both Gd silicate and Gd silicate:Eu nanoshells were further demonstrated to exhibit dual-modality MRI and optical imaging functions.

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