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Merck
CN

M2284

乙酰丙酮锰(III)

technical grade

别名:

2,4-戊二酮 锰(III) 衍生物, 乙酰丙酮锰, 锰(acac)3

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关于此项目

线性分子式:
Mn(C5H7O2)3
化学文摘社编号:
分子量:
352.26
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
238-188-3
MDL number:
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产品名称

乙酰丙酮锰(III), technical grade

InChI key

HYZQBNDRDQEWAN-LNTINUHCSA-K

InChI

1S/3C5H8O2.Mn/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

SMILES string

CC(=O)\C=C(\C)O[Mn](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

grade

technical grade

reaction suitability

core: manganese
reagent type: catalyst

mp

159-161 °C (dec.) (lit.)

Quality Level

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Application

氧化剂用于氧化酚类,β-二羰基化合物和硫醇。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

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Snider, B. B.; Patricia, J. J. et al.
The Journal of Organic Chemistry, 53, 2137-2137 (1988)
Nishino, H. Tategami, S. et al.
Bulletin of the Chemical Society of Japan, 64, 1800-1800 (1991)
The direct writing of plasmonic gold nanostructures by electron-beam-induced deposition.
Katja Höflich et al.
Advanced materials (Deerfield Beach, Fla.), 23(22-23), 2657-2661 (2011-05-04)
S S Arandjelovic et al.
Journal of B.U.ON. : official journal of the Balkan Union of Oncology, 14(2), 271-279 (2009-08-04)
To investigate the antitumor activity of two newly synthesized ruthenium(III) [Ru(III)] compounds carrying bidentate ligands: (acac)-acetylacetonate, [Ru(acac)3), and (tfac)-trifluoroacetylacetonate [Ru(tfac)3]. The activity of ruthenium(III) analogues was evaluated on HeLa, B16, and Femx cell lines for cytotoxicity in vitro using MTT
Gong-Jun Chen et al.
Dalton transactions (Cambridge, England : 2003), 39(44), 10637-10643 (2010-10-06)
Two Eu(III) complexes, [Eu(acac)(3)(dpq)] (1) and [Eu(acac)(3)(dppz)] CH(3)OH (2) {viz. acetylacetonate (acac), dipyrido[3,2-d:20,30-f]quinoxaline (dpq), dipyrido[3,2-a:20,30-c] phenazine (dppz)}, have been synthesized and their DNA binding, photo-induced DNA cleavage activity and cell cytotoxicity are studied. The complexes display significant binding propensity to

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