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Merck
CN

A-053

6-乙酰可待因标准液 溶液

1.0 mg/mL in acetonitrile, ampule of 1 mL, certified reference material, Cerilliant®

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经验公式（希尔记法）:
C20H23NO4
化学文摘社编号:
6703-27-1
分子量:
341.40
NACRES:
NA.24
PubChem Substance ID:
329770617
UNSPSC Code:
41116107
EC Number:
200-835-2
MDL number:
MFCD00190618

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InChI key

MFXFQKMUCYHPFQ-BKRJIHRRSA-N

InChI

1S/C20H23NO4/c1-11(22)24-16-7-5-13-14-10-12-4-6-15(23-3)18-17(12)20(13,19(16)25-18)8-9-21(14)2/h4-7,13-14,16,19H,8-10H2,1-3H3/t13-,14+,16-,19-,20-/m0/s1

SMILES string

COc1ccc2C[C@@H]3[C@@H]4C=C[C@H](OC(C)=O)[C@@H]5Oc1c2[C@]45CCN3C

grade

certified reference material

form

liquid

feature

SNAP-N-SPIKE®, SNAP-N-SHOOT®

packaging

ampule of 1 mL

manufacturer/tradename

Cerilliant®

drug control

Narcotic Licence Schedule A (Switzerland); estupefaciente (Spain); Decreto Lei 15/93: Tabela IA (Portugal), kontrollierte Droge in Deutschland

Quality Level

300

concentration

1.0 mg/mL in acetonitrile

technique(s)

gas chromatography (GC): suitable, liquid chromatography (LC): suitable

application(s)

forensics and toxicology

format

single component solution

storage temp.

−20°C

相关类别

General description

A Certified Snap-N-Spike® Solution suitable for use in LC/MS or GC/MS applications for clinical toxicology, forensic analysis, or urine drug testing. 6-Acetylcodeine is an analog of codeine and is sometimes present as an impurity in street heroin.

Legal Information

German
Dieses Produkt fällt unter das Betäubungsmittelgesetz (BtMG). Für eine Bestellung dieses Produktes ist eine Erlaubnis nach § 3 BtMG zwingend erforderlich, es sei denn, es greift eine Ausnahme von der Erlaubnispflicht nach § 4 oder § 26 BtMG.

English
This product is subject to the German Narcotics Act. A permit under Section 3 of the German Narcotics Act is mandatory for ordering this product unless an exemption from the permit requirement under Section 4 or Section 26 of the German Narcotics Act applies.
CERILLIANT is a registered trademark of Merck KGaA, Darmstadt, Germany
Snap-N-Shoot is a registered trademark of Cerilliant Corporation
Snap-N-Spike is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

35.6 °F - closed cup

flash_point_c

2 °C - closed cup

法规信息

监管及禁止进口产品
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Programmable temperature vaporizer applications in an high-resolution gas chromatographic method for the quantitation of impurities in illicit heroin.
E Bertol et al.
Journal of chromatography, 466, 384-389 (1989-04-19)
M Barroso et al.
Analytical and bioanalytical chemistry, 396(8), 3059-3069 (2010-03-03)
A simple procedure has been developed and validated for the qualitative and quantitative analysis of several opiates (morphine, 6-acetylmorphine, codeine, 6-acetylcodeine) and tramadol in hair. The analytes were extracted from within the matrix via an overnight incubation with methanol at
Guido Romano et al.
Forensic science international, 131(2-3), 98-102 (2003-02-19)
One of the most controversial point regarding the validity of hair testing is the risk of false positive due to external contamination. The aim of our experience is to verify if a 5 consecutive days contamination with a small amount
Steven Milo et al.
Cellular and molecular neurobiology, 26(4-6), 1011-1019 (2006-07-27)
1. Acetylation of morphine at the 6-position changes its pharmacology. To see if similar changes are seen with codeine, we examined the analgesic actions of codeine and 6-acetylcodeine. 2. Like codeine, 6-acetylcodeine is an effective analgesic systemically, supraspinally and spinally
Frank Musshoff et al.
Journal of analytical toxicology, 29(5), 345-352 (2005-08-18)
One month before (T-1) and 12 months after (T12) controlled intravenous administration of pharmaceutical heroin-HCl (10-1000 mg/d) in the context of a heroin-maintenance program, concentrations of opiates in head hair were determined (n = 46), using a validated gas chromatography-mass
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