8.14761
Tetrakis(triphenylphosphine)-palladium(0)
for synthesis
别名:
Tetrakis(triphenylphosphine)-palladium(0)
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关于此项目
线性分子式:
Pd(P(C6H5)3)4
化学文摘社编号:
分子量:
1155.56
UNSPSC Code:
12352103
EC Index Number:
238-086-9
NACRES:
NA.22
MDL number:
产品名称
Tetrakis(triphenylphosphine)-palladium(0), for synthesis
SMILES string
[Pd]([P](c%12ccccc%12)(c%11ccccc%11)c%10ccccc%10)([P](c9ccccc9)(c8ccccc8)c7ccccc7)([P](c6ccccc6)(c5ccccc5)c4ccccc4)[P](c3ccccc3)(c2ccccc2)c1ccccc1
InChI
1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
InChI key
NFHFRUOZVGFOOS-UHFFFAOYSA-N
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
103-107 °C
storage temp.
2-8°C
Quality Level
Analysis Note
Assay (ICP-OES): ≥ 97.0 %
Application
- Preparation of tricationic tris(pyridylpalladium(II)) metallacyclophane as an anion receptor.: This research explores the synthesis of a tricationic tris(pyridylpalladium(II)) metallacyclophane, showcasing its potential as an anion receptor. The study emphasizes the versatility of palladium complexes in developing new molecular structures for various applications (Danjo et al., 2022).
- A Ligand-Enabled Palladium-Catalyzed Highly para-Selective Difluoromethylation of Aromatic Ketones.: This study demonstrates the use of a palladium catalyst for highly selective difluoromethylation of aromatic ketones, highlighting the catalyst′s efficiency in organic synthesis and its potential for developing pharmaceuticals (Tu et al., 2018).
- Viable pathways for the oxidative addition of iodobenzene to palladium(0)-triphenylphosphine-carbonyl complexes: a theoretical study.: This theoretical investigation explores the oxidative addition mechanisms of iodobenzene to palladium(0)-triphenylphosphine-carbonyl complexes, providing insights into the reactivity and applications of palladium catalysts in organic synthesis (Pálinkás et al., 2017).
- Morita-Baylis-Hillman Reaction of α,β-Unsaturated Ketones with Allylic Acetates by the Combination of Transition-Metal Catalysis and Organomediation.: The paper discusses a novel Morita-Baylis-Hillman reaction facilitated by palladium(0) catalysts, demonstrating its utility in constructing complex molecular architectures for pharmaceutical synthesis (Li et al., 2016).
- Synthesis of a sterically crowded atropisomeric 1,8-diacridylnaphthalene for dual-mode enantioselective fluorosensing.: This research highlights the synthesis of a novel atropisomeric compound using palladium(0) catalysts, focusing on its application in enantioselective fluorosensing, crucial for biochemical analyses (Mei et al., 2006).
General description
Tetrakis(triphenylphosphine)-palladium(0) can be used to catalyze the formation of carbon-carbon bonds, the reduction of functional groups, the formation of carbon-metal bonds, and the deprotection of allyloxycarbonyl groups.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Tetrakis (triphenylphosphine) palladium (0)
Friesen R, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis, 1-7 (2017)
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