8.52133
Fmoc-Gln(Trt)-OPfp
Novabiochem®
别名:
Fmoc-Gln(Trt)-OPfp, N-α-Fmoc-N-γ-trityl-L-glutamine pentafluorophenyl ester
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关于此项目
经验公式（希尔记法）:
C45H33F5N2O5
化学文摘社编号:
分子量:
776.75
UNSPSC Code:
12352209
NACRES:
NA.22
MDL number:
SMILES string
Fc1c(c(c(c(c1F)F)OC(=O)[C@@H](NC(=O)OCC5c6c(cccc6)c7c5cccc7)CCC(=O)NC(c4ccccc4)(c3ccccc3)c2ccccc2)F)F
InChI
1S/C45H33F5N2O5/c46-37-38(47)40(49)42(41(50)39(37)48)57-43(54)35(51-44(55)56-26-34-32-22-12-10-20-30(32)31-21-11-13-23-33(31)34)24-25-36(53)52-45(27-14-4-1-5-15-27,28-16-6-2-7-17-28)29-18-8-3-9-19-29/h1-23,34-35H,24-26H2,(H,51,55)(H,52,53)/t35-/m0/s1
InChI key
OLYKAAWLZTVISS-DHUJRADRSA-N
product line
Novabiochem®
assay
≥98.0% (HPLC)
form
powder
reaction suitability
reaction type: Fmoc solid-phase peptide synthesis
manufacturer/tradename
Novabiochem®
application(s)
peptide synthesis
functional group
amide
storage temp.
15-25°C
Quality Level
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General description
Pre-formed pentafluorophenyl ester for coupling of glutamine amino-acid residues by Fmoc SPPS. Use enables bromophenol blue monitoring of amide bond formation.
Associated Protocols and Technical Articles
Cleavage and Deprotection Protocols for Fmoc SPPS
Literature references
[1] P. Sieber, et al. (1991) Tetrahedron Lett., 32, 739.
Associated Protocols and Technical Articles
Cleavage and Deprotection Protocols for Fmoc SPPS
Literature references
[1] P. Sieber, et al. (1991) Tetrahedron Lett., 32, 739.
Analysis Note
Color (visual): white to slight yellow to beige
Appearance of substance (visual): powder
Identity (IR): passes test
Optical rotation α 25/D (c=1 in dioxan): -8.0 - -5.0 °
Purity (TLC (0004)): <2% DCU
Assay (HPLC, area%): ≥ 98.0% (a/a)
Solubility (0.5 mmole in 3 ml DMF): clearly soluble
To see the solvent systems used for TLC of Novabiochem® products please click here.
Appearance of substance (visual): powder
Identity (IR): passes test
Optical rotation α 25/D (c=1 in dioxan): -8.0 - -5.0 °
Purity (TLC (0004)): <2% DCU
Assay (HPLC, area%): ≥ 98.0% (a/a)
Solubility (0.5 mmole in 3 ml DMF): clearly soluble
To see the solvent systems used for TLC of Novabiochem® products please click here.
Other Notes
Replaces: 04-12-1539
Legal Information
Novabiochem is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
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