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Merck
CN

05-5870

氯化亚铜

JIS special grade, ≥95.0%

别名:

一氯化铜

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关于此项目

线性分子式:
CuCl
化学文摘社编号:
分子量:
99.00
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
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grade

JIS special grade

vapor pressure

1.3 mmHg ( 546 °C)

assay

≥95.0%

form

solid

reaction suitability

reagent type: catalyst
core: copper

availability

available only in Japan

pH

5 (20 °C, 50 g/L)

bp

1490 °C (lit.)

mp

430 °C (lit.)

storage temp.

2-8°C

SMILES string

Cl[Cu]

InChI

1S/ClH.Cu/h1H;/q;+1/p-1

InChI key

OXBLHERUFWYNTN-UHFFFAOYSA-M

Application

作为自由基反应(如 α,β-不饱和酮的锡氢化作用)的引发剂表现出独特的性质。


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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Yi-Fan Zhao et al.
Journal of colloid and interface science, 448, 380-388 (2015-03-11)
Here we describe the development of versatile antifouling polyethersulfone (PES) filtration membranes modified via surface grafting of zwitterionic polymers from a reactive amphiphilic copolymer additive. Amphiphilic polyethersulfone-block-poly(2-hydroxyethyl methacrylate) (PES-b-PHEMA) was beforehand designed and used as the blending additive of PES
Xiaoliang Xu et al.
Organic letters, 12(5), 897-899 (2010-02-04)
Promoted by CuCl/CCl(4), a variety of sulfonyl azides and tertiary amines were successfully coupled to give sulfonyl amidine derivatives in good to excellent yields. A possible mechanism for this reaction is discussed.
Takayoshi Arai et al.
The Journal of organic chemistry, 73(13), 4903-4906 (2008-06-03)
A catalytic asymmetric Henry reaction has been developed with use of a sulfonyldiamine-CuCl complex as a catalyst. A series of new binaphthyl-containing sulfonyldiamine ligands (2a-h) were readily synthesized in two steps starting from commercially available chiral 1,2-diamines. The (R,R)-diamine-(R)-binaphthyl ligand