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Merck
CN

03323

苯并[k]荧蒽

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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经验公式(希尔记法):
C20H12
化学文摘社编号:
分子量:
252.31
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
205-916-6
Beilstein/REAXYS Number:
1873745
MDL number:
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InChI

1S/C20H12/c1-2-6-15-12-19-17-10-4-8-13-7-3-9-16(20(13)17)18(19)11-14(15)5-1/h1-12H

SMILES string

c1ccc2cc-3c(cc2c1)-c4cccc5cccc-3c45

InChI key

HAXBIWFMXWRORI-UHFFFAOYSA-N

grade

certified reference material, TraceCERT®

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

Quality Level

solubility

95% ethanol: <1 mg/mL at 20 °C, DMSO: <1 mg/mL at 20 °C, H2O: <1 mg/mL at 20 °C, acetone: 1-10 mg/mL at 20 °C, methanol: <1 mg/mL at 20 °C, toluene: 5-10 mg/mL at 20 °C

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

2-8°C

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Ion Mobility: TWCCSN2 value of 150.4 Å2 [M+H]+

The collision cross section (CCS) measurement was provided by Waters Corporation, using the SYNAPT XS mass spectrometer.
For a description and overview of how ion mobility enables the measurement of the CCS of an ion visit ims.waters.com
Further information on the SYNAPT XS mass spectrometer can be found on the IMS microsite and product webpage.

TWCCS measurements are expected to be within 2% of this reference value.

P/N 03323 is part of the Waters Extractables & Leachables UNIFI scientific library which can be downloaded from Waters Marketplace.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardEnvironment

signalword

Danger

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - PBT - vPvB


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K L Willett et al.
Toxicology and applied pharmacology, 177(3), 264-271 (2001-12-26)
Certainpolynuclear aromatic hydrocarbons (PAHs) such as benzo[a]pyrene (BaP) induce CYP1A-dependent enzyme activities. Because PAHs are ubiquitous environmental contaminants, and some are aryl hydrocarbon agonists, CYP1A has been used as a biomarker for PAH exposure. However, PAHs exist in the environment
Hiroyuki Masaki et al.
The Analyst, 130(9), 1253-1257 (2005-08-13)
We developed a device and some systems for detecting benzo[a]pyrene (B[a]P) and benzo[k]fluoranthene (B[k]F). The device uses a UV light-emitting diode that emits light with a wavelength of 370 nm and a violet laser diode that emits light with a
Annekatrin Dreyer et al.
Environmental science & technology, 39(11), 3918-3924 (2005-06-30)
To date, studies about historic PAH (polycyclic aromatic hydrocarbons) deposition at a regional scale have rarely been published. To address this research gap, we sampled 17 ombrotrophic peatlands across eastern Canada. The peat cores from hollows were dated with 210Pb
Petra Booij et al.
Environmental toxicology and chemistry, 30(4), 898-904 (2010-12-31)
In bioassays, exposure concentrations of test compounds are usually expressed as nominal concentrations. As a result of various processes, such as adsorption, degradation, or uptake, the actual freely dissolved concentration of the test compound may differ from the nominal concentration.
Shan Chen et al.
Environmental science & technology, 42(24), 9431-9436 (2009-01-30)
Japanese medakas (Oryzias latipes) and triolein-embedded cellulose acetate membranes (TECAMs) were exposed simultaneously to benzo[k]fluoranthene (BkF) in the static exposure system containing different concentrations of humic acid (HA). The concentration-response relationships of induced hepatic 7-ethoxysorufin-o-deethylase (EROD) activity were established in

商品

This application note describes the fast and efficient separation of the EU’s list of 15 + 1 polynuclear aromatic hydrocarbons (PAHs) using Ascentis® Express PAH HPLC column.

Ascentis® Express PAH column efficiently separates polynuclear aromatic hydrocarbons in EPA methods.

Compare PAH determination in olive oil: traditional GB 5009.265-2021 method vs. faster, simpler SPE with Supelclean EZ-POP NP; both meet criteria.

Highly accurate HPLC-FLD method for evaluating 15 PAHs in olive oil using Ascentis® Express PAH HPLC column and SPE cleanup, following GB 5009.265-2021.

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