13220
氯化亚锰 一水合物
≥97.0%, powder
别名:
Manganese dichloride monohydrate
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线性分子式:
MnCl2 · H2O
化学文摘社编号:
分子量:
143.86
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
231-869-6
MDL number:
产品名称
氯化亚锰 一水合物, ≥97.0%
InChI key
BXRRQHBNBXJZBQ-UHFFFAOYSA-L
InChI
1S/2ClH.Mn.H2O/h2*1H;;1H2/q;;+2;/p-2
SMILES string
O.Cl[Mn]Cl
assay
≥97.0%
form
powder
reaction suitability
core: manganese, reagent type: catalyst
impurities
≤0.01% heavy metals (as Pb)
anion traces
sulfate (SO42-): ≤1000 mg/kg
cation traces
Fe: ≤200 mg/kg
Quality Level
Application
Starting material for preparation of organomanganese chloride reagents; in combination with RLi or RMgX catalyzes reduction of vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- andstereo-selectively.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2
target_organs
Brain
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Cahiez, G.; Alami, M.
Tetrahedron Letters, 30, 3541-3541 (1989)
Fujii, H.; Oshima, K.; Utimoto, K.
Tetrahedron Letters, 32, 6147-6147 (1991)
Cahiez, G.; Laboue, B.
Tetrahedron Letters, 33, 4439-4439 (1992)
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