31653
锌
ACS reagent grade, ≥99.9%, granular, puriss. p.a., reag. ISO, reag. Ph. Eur.
别名:
Zn
产品名称
锌, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.9%, granular
等级
ACS reagent
puriss. p.a.
质量水平
Agency
USP/NF
reag. ISO
reag. Ph. Eur.
蒸汽压
1 mmHg ( 487 °C)
方案
≥99.9%
表单
granular
反应适用性
core: zinc
reagent type: catalyst
电阻率
5.8 μΩ-cm, 20°C
沸点
907 °C (lit.)
mp
420 °C (lit.)
密度
7.133 g/mL at 25 °C (lit.)
痕量阳离子
As: ≤0.1 mg/kg
Cd: ≤5 mg/kg
Cu: ≤10 mg/kg
Fe: ≤20 mg/kg
Pb: ≤50 mg/kg
Sn: ≤10 mg/kg
SMILES字符串
[Zn]
InChI
1S/Zn
InChI key
HCHKCACWOHOZIP-UHFFFAOYSA-N
应用
锌可用于制备有机锌试剂、Reformatsky 试剂 和 Simmons-Smith 试剂。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Use of activation methods for organozinc reagents.
Erdik E
Tetrahedron, 43(10), 2203-2212 (1987)
A scalable zinc activation procedure using dibal-h in a reformatsky reaction.
Girgis M J
Organic Process Research & Development, 13(6), 1094-1099 (2009)
Cyclopropanation of Electron-deficient Olefins with Dibromomethane by Ni (0) Complexes and Zinc.
Kanai H
Bulletin of the Chemical Society of Japan, 56(4), 1025-1029 (1983)
Highly efficient, general procedure for the preparation of alkylzinc reagents from unactivated alkyl bromides and chlorides.
Huo S
Organic Letters, 5(4), 423-425 (2003)
Cyclopropanes from an Easily Prepared, Highly Active Zinc?Copper Couple, Dibromomethane, and Olefins.
LeGoff E
The Journal of Organic Chemistry, 29(7), 2048-2050 (1964)
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