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Merck
CN

32986

柄曲菌素 溶液

~50 μg/mL in acetonitrile, analytical standard

别名:

3a,12c-二氢-8-羟基-6-甲氧基-7H-糠醛[3′,2′:4,5]呋[2,3-c]呫吨-7-酮

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关于此项目

经验公式(希尔记法):
C18H12O6
化学文摘社编号:
分子量:
324.28
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
EC Number:
200-835-2
Beilstein/REAXYS Number:
1299457
MDL number:
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InChI key

UTSVPXMQSFGQTM-UHFFFAOYSA-N

InChI

1S/C18H12O6/c1-21-11-7-12-13(8-5-6-22-18(8)24-12)17-15(11)16(20)14-9(19)3-2-4-10(14)23-17/h2-8,18-19H,1H3

SMILES string

COc1cc2OC3OC=CC3c2c4Oc5cccc(O)c5C(=O)c14

grade

analytical standard

shelf life

limited shelf life, expiry date on the label

concentration

~50 μg/mL in acetonitrile

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

cleaning products
cosmetics
food and beverages
personal care

format

single component solution

storage temp.

−20°C

Quality Level

General description

Sterigmatocystin is classified under the mycotoxin family of compounds. It is usually produced by the fungi of several species of Aspergillus.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Sterigmatocystin may be used as an analytical reference standard for the determination of the analyte in:
  • Grain samples by high-performance liquid chromatography-electrospray positive ionization-tandem mass spectrometry (HPLC-ESI+-MS/MS).
  • Beer samples by HPLC in conjunction with UV detection.

Analysis Note

purity : ≥96.0% (HPLC)

pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

42.8 °F - closed cup

flash_point_c

6 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
高风险级别生物产品--毒素类产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Determination of sterigmatocystin in beer by high performance liquid chromatography with ultraviolet detection.
Ver?ilovskis A, et al.
World Mycotoxin Journal, 1(2), 161-166 (2008)
Analytical method for the determination of sterigmatocystin in grains using high-performance liquid chromatography-tandem mass spectrometry with electrospray positive ionization.
Ver?ilovskis A, et al.
Journal of Chromatography A, 1157(1-2), 467-471 (2007)
Odile Cabaret et al.
Rapid communications in mass spectrometry : RCM, 25(19), 2704-2710 (2011-09-14)
Mycotoxins are secondary metabolites of filamentous fungi which can cause a wide range of systemic effects. Human health effects of inhaled mycotoxins remain poorly documented, despite the large amounts present, associated with air-borne particles. Among these mycotoxins, sterigmatocystin is one
Daniela Jakšić et al.
Archives of toxicology, 86(10), 1583-1591 (2012-06-01)
Aspergillus versicolor and A. flavus are primary colonizers in damp dwellings, and they produce sterigmatocystin (ST) and aflatoxin B1 (AFB(1)), respectively. These hepatotoxic and carcinogenic mycotoxins and their precursors and derivates possess a furofuran ring, which has proven responsible for
Xin Xing et al.
Molecular nutrition & food research, 55(5), 749-760 (2011-02-03)
Sterigmatocystin (ST), a mycotoxin commonly found in foodstuff and feedstuff, has been shown to be a carcinogenic mycotoxin in animal models. Many studies showed that the high level of ST contamination in grains might be related to the high incidence

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