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Merck
CN

424633

偶氮苯

98%

别名:

1,2-二苯基二氮烯;二苯基二氮烯

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关于此项目

线性分子式:
C6H5N=NC6H5
化学文摘社编号:
分子量:
182.22
UNSPSC Code:
12171500
NACRES:
NA.47
PubChem Substance ID:
EC Number:
203-102-5
Beilstein/REAXYS Number:
1819138
MDL number:
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InChI key

DMLAVOWQYNRWNQ-BUHFOSPRSA-N

InChI

1S/C12H10N2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H/b14-13+

SMILES string

c1ccc(cc1)\N=N\c2ccccc2

vapor pressure

1 mmHg ( 104 °C)

assay

98%

form

powder or crystals

autoignition temp.

890 °F

technique(s)

titration: suitable

bp

293 °C (lit.)

Quality Level

density

1.09 g/mL at 25 °C (lit.)

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

General description

偶氮苯是一种色原体和偶氮化合物,具有反式/顺式异构特性,这使其产生不同颜色的异构体。它是一种简单的偶氮芳烃化合物,在光的作用下偶氮键具有顺反异构化作用。

Application

偶氮苯及其衍生物的应用领域有机械和光学材料、光药理学和分子光开关(包括生物探针)。
由于人体组织在红光和近红外光下是半透明的,但在蓝光和紫外光下是不透明的,因此在医学和光药理学中,对于涉及将偶氮苯的反式和顺式异构体的吸收转移到更长波长的应用,偶氮苯非常重要。

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Muta. 2 - STOT RE 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

212.0 °F - closed cup

flash_point_c

100.0 °C - closed cup

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

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Lot/Batch Number

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Michael S Scholz et al.
The journal of physical chemistry. A, 121(34), 6413-6419 (2017-08-05)
Because of their high photoisomerization efficiencies, azobenzenes and their functionalized derivatives are used in a broad range of molecular photoswitches. Here, the photochemical properties of the trans isomers of protonated azobenzene (ABH
NIR-triggered anticancer drug delivery by upconverting nanoparticles with integrated azobenzene-modified mesoporous silica.
Jianan Liu et al.
Angewandte Chemie (International ed. in English), 52(16), 4375-4379 (2013-03-16)
Osvaldo N Oliveira et al.
Advances in colloid and interface science, 116(1-3), 179-192 (2005-11-01)
This paper brings an overview of photoisomerization-derived properties in azobenzene-containing nanostructured films produced with the Langmuir-Blodgett (LB) and layer-by-layer (LbL) methods. Emphasis was placed on the optical storage and formation of surface-relief gratings (SRGs), where the distinctive properties of the
Jing Sun et al.
Biomacromolecules, 13(11), 3736-3746 (2012-09-26)
Hydrophilic or amphiphilic macromolecules are common organic matrices used to encapsulate and protect fragile drugs such as proteins. Polymer cargoes are in addition designed for remote control of protein delivery, upon imparting the macromolecules with stimuli-responsive properties, such as light-triggered
Seungwoo Lee et al.
Advanced materials (Deerfield Beach, Fla.), 24(16), 2069-2103 (2012-03-29)
This review demonstrates directional photofluidization lithography (DPL), which makes it possible to fabricate a generic and sophisticated micro/nanoarchitecture that would be difficult or impossible to attain with other methods. In particular, DPL differs from many of the existing micro/nanofabrication methods

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