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Merck
CN

43861

Supelco

呋喃

analytical standard

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关于此项目

经验公式(希尔记法):
C4H4O
化学文摘社编号:
分子量:
68.07
Beilstein:
103221
EC 号:
MDL编号:
UNSPSC代码:
85151701
PubChem化学物质编号:
NACRES:
NA.24
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等级

analytical standard

质量水平

蒸汽密度

2.35 (vs air)

蒸汽压

1672 mmHg ( 55 °C)
31.66 psi ( 55 °C)
493 mmHg ( 20 °C)
9.22 psi ( 20 °C)

方案

≥98.0% (GC)

保质期

limited shelf life, expiry date on the label

包含

~0.025% 2,6-di-tert-4-methylphenol as stabilizer

expl. lim.

14.3 %

技术

HPLC: suitable
gas chromatography (GC): suitable

折射率

n20/D 1.421 (lit.)
n20/D 1.421

沸点

32 °C/758 mmHg (lit.)

密度

0.936 g/mL at 25 °C (lit.)

应用

cleaning products
cosmetics
environmental
food and beverages
personal care

包装形式

neat

储存温度

2-8°C

SMILES字符串

c1ccoc1

InChI

1S/C4H4O/c1-2-4-5-3-1/h1-4H

InChI key

YLQBMQCUIZJEEH-UHFFFAOYSA-N

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一般描述

Furan is a clear and colorless liquid, and a bimolecular heterocycle, which can be used to trap unstable intermediates containing highly reactive species, via Diels-Alder cycloaddition reactions.
Furan, a naturally occurring compound associated with the flavor of food, is found at very low levels in a variety of food products and beverages. It finds applications as a solvent for resins and lacquers as well as in the preparation of organic compounds, in pharmaceuticals, etc. Furan is also reportedly identified in heat treated food products, including cooked chicken, fish protein concentrate, caramel back, canned meat, bread, coffee, etc.
This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

应用

Furan can undergo Diels-Alder [4+2] cycloaddition reaction with maleic anhydride to form the corresponding exo and endo furan-maleic anhydride adducts.
Furan may be used as an analytical reference standard for the quantification of the analyte in heat-processed foods using gas chromatography-mass spectrometry (GC-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

警示用语:

Danger

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 1B - Flam. Liq. 1 - Muta. 2 - Skin Irrit. 2 - STOT RE 2

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

-32.8 °F - closed cup

闪点(°C)

-36 °C - closed cup

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Analysis of furan in heat-processed foods in China by automated headspace gas chromatography-mass spectrometry (HS-GC-MS)
Nie P-S, et al.
Food Control, 30(1), 62-68 (2013)
Furan in Food ? a Review
Vranova J and Ciesarova Z
Czech Journal of Food Sciences, 27(1), 1-10 (2009)
Synthetic applications of furan Diels-Alder chemistry
Kappe O.C, et al.
Tetrahedron, 53(42), 14179-14233 (1997)
Simultaneous determination of furan and 2-alkylfurans in heat-processed foods by automated static headspace gas chromatography-mass spectrometry
Shen M, et al.
LWT--Food Science and Technology, 72, 44-54 (2016)
Rialet Pieters et al.
Environment international, 66, 71-78 (2014-02-18)
In South Africa, 26-50% of households use solid fuel for cooking food and heating houses. When used as fuel, wood and chlorinated waste are known sources of polychlorinated dibenzo-para-dioxins, polychlorinated dibenzofurans (PCDD/Fs), and polychlorinated biphenyls (PCBs). Here, we compare PCDD/F

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