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Merck
CN

44920

Sigma-Aldrich

乙酰丙酮铁 III

purum, ≥97.0% (RT)

别名:

2,4-戊二酮 铁(III) 衍生物, 2,4-戊二酮铁(III), Fe(acac)3, 乙酰丙酮铁

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About This Item

线性分子式:
Fe(C5H7O2)3
CAS Number:
分子量:
353.17
Beilstein:
4157960
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23

等级

purum

质量水平

方案

≥97.0% (RT)

表单

powder

反应适用性

core: iron
reagent type: catalyst

mp

180-182 °C (dec.) (lit.)
180-190 °C (dec.)

密度

5.24 g/mL at 25 °C (lit.)

SMILES字符串

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

AQBLLJNPHDIAPN-LNTINUHCSA-K

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一般描述

Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)3, is a coordination compound that is highly soluble in organic solvents. It is used as a precursor in the preparation of iron-containing materials and thin films, which are important in electronics and coatings. Additionally, it is also as a catalyst in organic reactions, particularly in the synthesis of organic compounds and polymerization processes.

应用

用于高结晶(Zn,Fe)Fe2O4 薄膜的 MOCVD 前体和这些薄膜的磁性测量。
Iron(III) acetylacetonate can be used as:


  • A precursor in the synthesis of Fe3O4/carbon composite fibers via forcespinning. This fiber material is suitable for use as anode materials in lithium-ion batteries.
  • A precursor in the synthesis of iron-based metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.
  • A catalyst in the controlled living radical polymerization of vinyl acetate to synthesis of polymers with controlled molecular weights.
  • A precursor to synthesize iron-doped titania (Fe-TiO2) photocatalysts for the potential applications in photocatalytic reactions.
  • A MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.
  • A precursor in the synthesis of Iron-oxide nanoparticles in the development of carbon nanofiber (CNF) based anodes for lithium-ion batteries.
  • A precursor in the synthesis of ferrimagnetic iron oxide nanoparticles (magnetite or maghemite) with various morphologies, which are employed in biomedical applications such as hyperthermia, magnetic resonance imaging (MRI), and drug delivery.
  • A precursor in the synthesis of magnetite nanoparticles via solvothermal synthesis. The resulting nanoparticles are smaller than 20 nm, exhibit uniform size, high crystallinity, and good dispersibility in organic solvents. These properties make them suitable for applications in, nanocomposite preparation, and film deposition. (3)
  • A precursor in the synthesis of superparamagnetic iron oxide nanoparticles by various methods such as gas-phase deposition, pulsed laser ablation, power ball milling, chemical co-precipitation, micro-emulsions, hydrothermal synthesis. These nanoparticles find applications in tissue engineering biosensors, magnetic resonance imaging.

特点和优势

Iron(III) acetylacetonate exhibits
  • Ethanol, Acetone, Benzene, dichloromethane, Toluene, Chloroform
  • Suitable for Iron catalysed cross-coupling reaction

其他说明

用于格氏反应的催化剂,添加酸性氯化物可生成酮。

象形图

CorrosionExclamation mark

警示用语:

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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