所有图片(1)
About This Item
线性分子式:
Fe(C5H7O2)3
CAS Number:
分子量:
353.17
Beilstein:
4157960
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
等级
purum
质量水平
方案
≥97.0% (RT)
表单
powder
反应适用性
core: iron
reagent type: catalyst
mp
180-182 °C (dec.) (lit.)
180-190 °C (dec.)
密度
5.24 g/mL at 25 °C (lit.)
SMILES字符串
CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
InChI
1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
InChI key
AQBLLJNPHDIAPN-LNTINUHCSA-K
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一般描述
Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)3, is a coordination compound that is highly soluble in organic solvents. It is used as a precursor in the preparation of iron-containing materials and thin films, which are important in electronics and coatings. Additionally, it is also as a catalyst in organic reactions, particularly in the synthesis of organic compounds and polymerization processes.
应用
用于高结晶(Zn,Fe)Fe2O4 薄膜的 MOCVD 前体和这些薄膜的磁性测量。
Iron(III) acetylacetonate can be used as:
- A precursor in the synthesis of Fe3O4/carbon composite fibers via forcespinning. This fiber material is suitable for use as anode materials in lithium-ion batteries.
- A precursor in the synthesis of iron-based metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.
- A catalyst in the controlled living radical polymerization of vinyl acetate to synthesis of polymers with controlled molecular weights.
- A precursor to synthesize iron-doped titania (Fe-TiO2) photocatalysts for the potential applications in photocatalytic reactions.
- A MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.
- A precursor in the synthesis of Iron-oxide nanoparticles in the development of carbon nanofiber (CNF) based anodes for lithium-ion batteries.
- A precursor in the synthesis of ferrimagnetic iron oxide nanoparticles (magnetite or maghemite) with various morphologies, which are employed in biomedical applications such as hyperthermia, magnetic resonance imaging (MRI), and drug delivery.
- A precursor in the synthesis of magnetite nanoparticles via solvothermal synthesis. The resulting nanoparticles are smaller than 20 nm, exhibit uniform size, high crystallinity, and good dispersibility in organic solvents. These properties make them suitable for applications in, nanocomposite preparation, and film deposition. (3)
- A precursor in the synthesis of superparamagnetic iron oxide nanoparticles by various methods such as gas-phase deposition, pulsed laser ablation, power ball milling, chemical co-precipitation, micro-emulsions, hydrothermal synthesis. These nanoparticles find applications in tissue engineering biosensors, magnetic resonance imaging.
特点和优势
Iron(III) acetylacetonate exhibits
- Ethanol, Acetone, Benzene, dichloromethane, Toluene, Chloroform
- Suitable for Iron catalysed cross-coupling reaction
其他说明
用于格氏反应的催化剂,添加酸性氯化物可生成酮。
警示用语:
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
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