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Merck
CN

44920

乙酰丙酮铁 III

greener alternative

purum, ≥97.0% (RT)

别名:

2,4-戊二酮 铁(III) 衍生物, 2,4-戊二酮铁(III), Fe(acac)3, 乙酰丙酮铁

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关于此项目

线性分子式:
Fe(C5H7O2)3
化学文摘社编号:
分子量:
353.17
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
237-853-5
Beilstein/REAXYS Number:
4157960
MDL number:
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grade

purum

Quality Segment

assay

≥97.0% (RT)

form

powder

reaction suitability

core: iron, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

180-182 °C (dec.) (lit.), 180-190 °C (dec.)

density

5.24 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

AQBLLJNPHDIAPN-LNTINUHCSA-K

General description

Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)3, is a coordination compound that is highly soluble in organic solvents. It is used as a precursor in the preparation of iron-containing materials and thin films, which are important in electronics and coatings. Additionally, it is also as a catalyst in organic reactions, particularly in the synthesis of organic compounds and polymerization processes.

Application

用于高结晶(Zn,Fe)Fe2O4 薄膜的 MOCVD 前体和这些薄膜的磁性测量。
Iron(III) acetylacetonate can be used as:


  • A precursor in the synthesis of Fe3O4/carbon composite fibers via forcespinning. This fiber material is suitable for use as anode materials in lithium-ion batteries.
  • A precursor in the synthesis of iron-based metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.
  • A catalyst in the controlled living radical polymerization of vinyl acetate to synthesis of polymers with controlled molecular weights.
  • A precursor to synthesize iron-doped titania (Fe-TiO2) photocatalysts for the potential applications in photocatalytic reactions.
  • A MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.
  • A precursor in the synthesis of Iron-oxide nanoparticles in the development of carbon nanofiber (CNF) based anodes for lithium-ion batteries.
  • A precursor in the synthesis of ferrimagnetic iron oxide nanoparticles (magnetite or maghemite) with various morphologies, which are employed in biomedical applications such as hyperthermia, magnetic resonance imaging (MRI), and drug delivery.
  • A precursor in the synthesis of magnetite nanoparticles via solvothermal synthesis. The resulting nanoparticles are smaller than 20 nm, exhibit uniform size, high crystallinity, and good dispersibility in organic solvents. These properties make them suitable for applications in, nanocomposite preparation, and film deposition. (3)
  • A precursor in the synthesis of superparamagnetic iron oxide nanoparticles by various methods such as gas-phase deposition, pulsed laser ablation, power ball milling, chemical co-precipitation, micro-emulsions, hydrothermal synthesis. These nanoparticles find applications in tissue engineering biosensors, magnetic resonance imaging.

Features and Benefits

Iron(III) acetylacetonate exhibits
  • Ethanol, Acetone, Benzene, dichloromethane, Toluene, Chloroform
  • Suitable for Iron catalysed cross-coupling reaction
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Other Notes

用于格氏反应的催化剂,添加酸性氯化物可生成酮。


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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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