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Merck
CN

56671

(±)-环氧丙烷

analytical standard

别名:

(±)-甲基环氧乙烷, 1,2-环氧丙烷

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关于此项目

经验公式(希尔记法):
C3H6O
化学文摘社编号:
分子量:
58.08
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
200-879-2
Beilstein/REAXYS Number:
79763
MDL number:
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InChI key

GOOHAUXETOMSMM-UHFFFAOYSA-N

InChI

1S/C3H6O/c1-3-2-4-3/h3H,2H2,1H3

SMILES string

CC1CO1

grade

analytical standard

vapor density

2 (vs air)

vapor pressure

29.43 psi ( 55 °C), 8.59 psi ( 20 °C)

assay

≥99.7% (GC)

autoignition temp.

1378 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

37 %

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

Quality Level

bp

34 °C (lit.)

mp

−112 °C (lit.)

density

0.83 g/mL at 25 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

2-8°C

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General description

这种物质被列入EU第10/2011号法规中用于与食品接触的塑料的正面清单。请点击此处查看列入10/2011 的所有化合物的参考物质。
This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

Application

(±)-环氧丙烷已被用作制备磁共振(MR)造影剂的起始材料,如Β-EgadMe和Β-EgadMe,可用于检测Β-半乳糖苷酶在体内的存在。
有关合适仪器技术的更多信息,请参考产品′分析证书。如需进一步支持,请联系技术服务部门。

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 1 - Muta. 1B - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-36.4 °F - Equilibrium method

flash_point_c

-38 °C - Equilibrium method

ppe

Faceshields, Gloves, Goggles

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Lauren M Urbanczyk-Pearson et al.
Nature protocols, 3(3), 341-350 (2008-03-08)
The preparation of beta-EgadMe and alpha-EgadMe, magnetic resonance (MR) contrast agents that can be used for in vivo detection of beta-galactosidase, is described. Diastereomerically pure beta-EgadMe can be synthesized by kinetically resolving the starting material as described in Step 1.
Yuqiang Qian et al.
ACS applied materials & interfaces, 3(9), 3709-3717 (2011-08-23)
Natural vermiculite was modified by cation exchange with long-chain quaternary alkylammonium salts and then dispersed in polyether-based polyols with different structures and ethylene oxide/propylene oxide ratios. The dispersions were evaluated by X-ray scattering and rheology. In all polyol dispersions tested
Nitai Ecker et al.
Autophagy, 6(7), 879-890 (2010-07-22)
A number of signaling mechanisms have been implicated in the regulation of autophagic trafficking. TOR kinase activity, cAMP levels, and the GAAC pathway have all been suggested to be involved. Here, we closely analyzed the stimuli that underlie induction of
Javix Thomas et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(16), 4582-4587 (2011-03-25)
Chirality recognition in the hydrogen-bonded glycidol···propylene oxide complex has been studied by using rotational spectroscopy and ab initio calculations. An extensive conformational search has been performed for this binary adduct at the MP2/6-311++G(d,p) level of theory and a total of
Kelli L Hvorecny et al.
Structure (London, England : 1993), 25(5), 697-707 (2017-04-11)
Pseudomonas aeruginosa secretes an epoxide hydrolase with catalytic activity that triggers degradation of the cystic fibrosis transmembrane conductance regulator (CFTR) and perturbs other host defense networks. Targets of this CFTR inhibitory factor (Cif) are largely unknown, but include an epoxy-fatty

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