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Merck
CN

74731

1-十八硫醇

purum, ≥95.0% (GC)

别名:

Mercaptan C18, 十八硫醇, 正十八硫醇

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关于此项目

线性分子式:
CH3(CH2)17SH
化学文摘社编号:
分子量:
286.56
UNSPSC Code:
12352300
NACRES:
NA.23
PubChem Substance ID:
EC Number:
220-744-1
Beilstein/REAXYS Number:
1811934
MDL number:
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产品名称

1-十八硫醇, purum, ≥95.0% (GC)

InChI key

QJAOYSPHSNGHNC-UHFFFAOYSA-N

InChI

1S/C18H38S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h19H,2-18H2,1H3

SMILES string

CCCCCCCCCCCCCCCCCCS

grade

purum

assay

≥95.0% (GC)

form

solid

bp

204-210 °C/11 mmHg (lit.)

mp

30-33 °C (lit.)

density

0.847 g/mL at 25 °C (lit.)

Quality Level

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Analysis Note

熔化时可能含有沉淀

Application

ODT用于将硫醇化分子沉积到金基质的表面上,例如
  • 金石英晶体谐振器上的SAM。
  • 在原子力显微镜探针的尖端。
  • 电容式传感器。

General description

1-十八烷硫醇(ODT)是一种具有18碳烷基链的水溶性硫化合物,它与过渡金属(如金)形成强疏水性组装体,并在此类过渡金属表面形成自组装单层(SAM)。硫醇膜与金属电极表面共价键合时,显示出电致伸缩现象,导致电容变化。ODT SAM具有疏水表面,接触角为102oC。

pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

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Polarization modulation Fourier transform infrared reflectance measurements of thin films and monolayers at metal surfaces utilizing real-time sampling electronics.
Barbara BJ, et al
Analytical Chemistry, 63(1), 55-60 (1991)
Ken Kobayashi et al.
Journal of chromatography. A, 1110(1-2), 95-101 (2006-02-14)
Three types of thiol compounds (n-octadecanethiol, thiophenol, and 2-phenylethanethiol) were used to modify the gold-coated polystyrene particles (dp. 5microm) to prepare a stationary phase for capillary liquid chromatography through the formation of self-assembled monolayer. The column with n-octadecanethiol-modified gold-coated polystyrene
Yanxia Hou et al.
Langmuir : the ACS journal of surfaces and colloids, 21(9), 4058-4065 (2005-04-20)
To make ultrathin films for the fabrication of artificial olfactory systems, odorant biosensors, we have investigated mixed Langmuir and Langmuir-Blodgett films of odorant-binding protein/amphiphile. Under optimized experimental conditions (phosphate buffer solution, pH 7.5, OBP-1F concentration of 4 mg L(-1), target
Qi-Shu Qu et al.
Journal of chromatography. A, 1198-1199, 95-100 (2008-06-10)
Monodispersed spherical gold particles synthesized and modified with n-octadecanethiol (C18-Au) were packed into a 100 microm I.D. capillary column and tested in capillary high-performance liquid chromatography (microHPLC). To the best of our knowledge, this represents the first report on the
Tao Zhang et al.
Nano letters, 10(11), 4738-4741 (2010-10-12)
We report studies on surface modification of graphene with 1-octadecanethiol and its application as heavy metal sensors. The alkanethiol molecules can self-assemble into large-scale highly ordered monolayers on single-layer graphene regardless of the roughness of graphene surfaces inherited from the

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