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Merck
CN

74731

1-十八硫醇

purum, ≥95.0% (GC)

别名:

Mercaptan C18, 十八硫醇, 正十八硫醇

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关于此项目

线性分子式:
CH3(CH2)17SH
化学文摘社编号:
分子量:
286.56
Beilstein:
1811934
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.23
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等级

purum

质量水平

方案

≥95.0% (GC)

表单

solid

沸点

204-210 °C/11 mmHg (lit.)

mp

30-33 °C (lit.)

密度

0.847 g/mL at 25 °C (lit.)

SMILES字符串

CCCCCCCCCCCCCCCCCCS

InChI

1S/C18H38S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h19H,2-18H2,1H3

InChI key

QJAOYSPHSNGHNC-UHFFFAOYSA-N

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一般描述

1-十八烷硫醇(ODT)是一种具有18碳烷基链的水溶性硫化合物,它与过渡金属(如金)形成强疏水性组装体,并在此类过渡金属表面形成自组装单层(SAM)。硫醇膜与金属电极表面共价键合时,显示出电致伸缩现象,导致电容变化。ODT SAM具有疏水表面,接触角为102oC。

应用

ODT用于将硫醇化分子沉积到金基质的表面上,例如
  • 金石英晶体谐振器上的SAM。
  • 在原子力显微镜探针的尖端。
  • 电容式传感器。

分析说明

熔化时可能含有沉淀

象形图

Exclamation markEnvironment

警示用语:

Warning

危险声明

危险分类

Aquatic Acute 1 - Skin Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Polarization modulation Fourier transform infrared reflectance measurements of thin films and monolayers at metal surfaces utilizing real-time sampling electronics.
Barbara BJ, et al
Analytical Chemistry, 63(1), 55-60 (1991)
Yanxia Hou et al.
Langmuir : the ACS journal of surfaces and colloids, 21(9), 4058-4065 (2005-04-20)
To make ultrathin films for the fabrication of artificial olfactory systems, odorant biosensors, we have investigated mixed Langmuir and Langmuir-Blodgett films of odorant-binding protein/amphiphile. Under optimized experimental conditions (phosphate buffer solution, pH 7.5, OBP-1F concentration of 4 mg L(-1), target
Ken Kobayashi et al.
Journal of chromatography. A, 1110(1-2), 95-101 (2006-02-14)
Three types of thiol compounds (n-octadecanethiol, thiophenol, and 2-phenylethanethiol) were used to modify the gold-coated polystyrene particles (dp. 5microm) to prepare a stationary phase for capillary liquid chromatography through the formation of self-assembled monolayer. The column with n-octadecanethiol-modified gold-coated polystyrene
Diego Millo et al.
Colloids and surfaces. B, Biointerfaces, 81(1), 212-216 (2010-08-03)
Hybrid bilayer lipid membranes (HBMs) were built on roughened silver electrodes exhibiting surface-enhanced Raman scattering (SERS) activity. The HBM consisted of a first layer of octadecanethiol (ODT) directly bound to the electrode surface, on which a second layer of 1,2-diphytanoyl-sn-glycero-3-phosphocholine
Jimin Yao et al.
Advanced materials (Deerfield Beach, Fla.), 22(10), 1102-1110 (2010-04-20)
Plasmonic crystals fabricated with precisely controlled arrays of subwavelength metal nanostructures provide a promising platform for sensing and imaging of surface binding events with micrometer spatial resolution over large areas. Soft nanoimprint lithography provides a robust, cost-effective method for producing

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