902217
Ir[dFFppy]2-(4,4′-dCF3bpy)PF6
≥95%, powder or crystals
可持续性特点
别名:
Ir photocatalyst, Photocatalyst
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关于此项目
经验公式（希尔记法）:
C34H16F18IrN4P
化学文摘社编号:
分子量:
1045.68
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
产品名称
Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%
assay
≥95%
form
powder or crystals
reaction suitability
core: iridium, reagent type: catalyst
reaction type: Photocatalysis
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Sustainability features
mp
>300 °C
photocatalyst activation
450 nm
SMILES string
[Ir+]741([NH]8=C(c9c7cc(cc9F)F)C=CC(=C8)F)([NH]5=CC(=CC=C5c6c4cc(cc6F)F)F)[NH]2=CC=C(C=C2C3=CC(=CC=[NH]31)C(F)(F)F)C(F)(F)F.F[P-](F)(F)(F)(F)F
InChI key
UCNIZYCFAFBGQB-UHFFFAOYSA-N
General description
Sustainability Features: Aligned with Green Chemistry principle, ′Catalysis,′ this product is an advanced Hoveyda-Grubbs type catalyst for specialized metathesis applications. It provides superior performance in sterically demanding ring-closing metathesis reactions. Click here for more information.
Application
Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
存储类别
11 - Combustible Solids
WGK
WGK 3
闪点 (F)
Not applicable
闪点 (°C)
Not applicable