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Merck
CN

919780

Sigma-Aldrich

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads

solid

别名:

Pd(dppf)Cl2

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About This Item

线性分子式:
(C17H14P)2Fe . PdCl2
CAS Number:
MDL编号:
UNSPSC代码:
12352103
NACRES:
NA.22

Product Name

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads,

表单

solid

质量水平

组成

~ 4 wt.% loading of catalyst

反应适用性

reagent type: catalyst
reaction type: Cross Couplings

SMILES字符串

[Pd+2].[Fe+2].P(c6c[c-H]cc6)(c5ccccc5)c4ccccc4.P(c3c[c-H]cc3)(c2ccccc2)c1ccccc1.[Cl-].[Cl-]

InChI

1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q2*-1;;;2*+2/p-2

InChI key

NXQGGXCHGDYOHB-UHFFFAOYSA-L

相关类别

应用

Catalyst for C-C and C-N coupling reaction.
Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:
  • Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
  • Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
  • Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

For larger scale uses, product also available in powdered form (697230) & (931217)

象形图

Health hazard

警示用语:

Danger

危险声明

危险分类

Carc. 1B Inhalation

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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