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Merck
CN

945528

溴化铜

≥99.5%, purum

别名:

一溴化铜

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关于此项目

线性分子式:
CuBr
化学文摘社编号:
分子量:
143.45
UNSPSC Code:
12352324
MDL number:
Assay:
≥99.5%
Form:
powder or chunks
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grade

purum

Quality Level

assay

≥99.5%

form

powder or chunks

reaction suitability

reagent type: catalyst
core: copper
reaction type: click chemistry

color

white to green

mp

504 °C (lit.)

density

4.71 g/mL at 25 °C (lit.)

SMILES string

[Cu]Br

InChI

1S/BrH.Cu/h1H;/q;+1/p-1

InChI key

NKNDPYCGAZPOFS-UHFFFAOYSA-M

General description

Copper(I) bromide (CuBr) is an inorganic salt commonly used as a catalyst or a source of Cu(I) in organic synthesis.

Application

Copper(I) bromide has been used in:
  • The synthesis of tertiary alkyl amines via photoinduced copper catalysed nucelophilic substitution
  • The synthesis of complex secondary amines via photoredox-catalyzed four component click reactions
  • The synthesis of mechanophore polymers that rupture (C-C) via heterolytic, homolytic and concerted pathways
  • The intramolecular annulation of diaryl cyclic chloranes and bromanes

Features and Benefits

This high quality copper(I) bromide is tested to be extremely low in iron impurities. It is suitable for use in further copper mediated synthesis and catalysis, especially in copper mediated azide-alkyne cycloaddition click chemistry (CuAAC).


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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

存储类别

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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全球贸易项目编号

货号GTIN
945528-100G04065273688344
945528-1KG04065273688351