94882
马鞭草烯醇
analytical standard
别名:
(-)-4,6,6-三甲基二环[3.1.1]庚-3-烯-2-酮, 马鞭烯酮
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关于此项目
经验公式（希尔记法）:
C10H14O
化学文摘社编号:
分子量:
150.22
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
EC Number:
214-807-2
Beilstein/REAXYS Number:
1907623
MDL number:
产品名称
马鞭草烯醇, analytical standard
InChI key
DCSCXTJOXBUFGB-JGVFFNPUSA-N
InChI
1S/C10H14O/c1-6-4-9(11)8-5-7(6)10(8,2)3/h4,7-8H,5H2,1-3H3/t7-,8+/m0/s1
SMILES string
CC1=CC(=O)[C@H]2C[C@@H]1C2(C)C
grade
analytical standard
assay
≥99.0% (sum of enantiomers, GC)
optical activity
[α]20/D −170±12°, neat
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
refractive index
n20/D 1.496 (lit.)
n20/D 1.497
bp
227-228 °C (lit.)
density
0.975 g/mL at 20 °C (lit.)
application(s)
cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
format
neat
storage temp.
2-8°C
Quality Level
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Other Notes
单萜手性构件单元；异构化生成 2(10)-蒎烯-4-酮；五环化作用；氧化裂解成低蒎酮酸
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Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
185.0 °F - closed cup
flash_point_c
85 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
P.H.J. Carlsen et al.
Acta Chemica Scandinavica. Series B, 38, 501-501 (1984)
K.J. Moriarty et al.
Organometallics, 8, 1512-1512 (1989)
G. Ohloff et al.
Helvetica Chimica Acta, 60, 1496-1496 (1977)
R A Progar et al.
Journal of economic entomology, 106(1), 221-228 (2013-03-02)
Mountain pine beetle, Dendroctonus ponderosae Hopkins (Coleoptera: Curculionidae: Scolytinae), is among the primary causes of mature lodgepole pine, Pinus contorta variety latifolia mortality. Verbenone is the only antiaggregant semiochemical commercially available for reducing mountain pine beetle infestation of lodgepole pine.
Mitsuo Miyazawa et al.
Drug metabolism and disposition: the biological fate of chemicals, 31(8), 1049-1053 (2003-07-18)
(-)-Verbenone, a monoterpene bicyclic ketone, is a component of the essential oil from rosemary species such as Rosmarinus officinalis L., Verbena triphylla, and Eucalyptus globulus and is used for an herb tea, a spice, and a perfume. In this study
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