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线性分子式:
(CH3COO)2Hg
化学文摘社编号:
分子量:
318.68
UNSPSC Code:
12352103
NACRES:
NB.24
PubChem Substance ID:
EC Number:
216-491-1
Beilstein/REAXYS Number:
3563831
MDL number:
Assay:
≥98.0%
Grade:
ACS reagent
Form:
powder
grade
ACS reagent
Quality Level
assay
≥98.0%
form
powder
reaction suitability
reagent type: catalyst
core: mercury
impurities
≤0.01% insolubles
reduction residue
≤0.02%
mp
179-182 °C (lit.)
anion traces
chloride (Cl-): ≤0.005%, nitrate (NO3-): ≤0.005%, sulfate (SO42-): ≤0.005%
cation traces
Fe: ≤0.001%, Hg+: ≤0.4%, other heavy metals (as Pb): ≤0.002%
SMILES string
CC(=O)O[Hg]OC(C)=O
InChI
1S/2C2H4O2.Hg/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
InChI key
BRMYZIKAHFEUFJ-UHFFFAOYSA-L
General description
Mercury(II) acetate is a reagent mainly used in oxymercuration-demercuration reaction.
Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed. It participates in the synthesis of nitrate esters, acetate esters, alcohols and ethers.
Application
Due to its strong affinity towards sulfur, it finds application as a reagent in desulfurization reactions. Mercury(II) acetate may be used in the preparation of mercury(II) acetate-Nafion modified electrode, which can be used in anodic stripping voltammetry for the analysis of lead and copper ions in waste water samples.
Mercury(II) acetate may be used in the preparation of 2-benzylidene-3(2H)-benzofuran-3-ones (aurones). It may be used in the hydrothermal synthesis of [Hg2(apca)2]n [apca = 3-aminopyrazine-2-carboxylate], a new mercury(I)-organic framework based on Hg22 + dumbbell.
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Danger
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
监管及禁止进口产品
此项目有
Mercury (II) Acetate.
Dejmek M.
Synlett, 23(19), 2867-2868 (2012)
Polarography of olefin-mercury (II) acetate addition compounds.
Fleet B and Jee RD.
J. Electroanal. Chem. Interfac. Electrochem., 25(3), 397-408 (1973)
Mercury-assisted solvolyses of alkyl halides: Simple procedures for the preparation of nitrate esters, acetate esters, alcohols and ethers.
McKillop A and Ford ME.
Tetrahedron, 30(15), 2467-2475 (1974)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 176109-100G | 04061838752703 |
| 176109-5G | 04061838752710 |
| 176109-500G | 04061835346479 |


