InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
SMILES string
Cl[Ti](Cl)(Cl)Cl
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
vapor pressure
24.09 psi ( 55 °C), 6.93 psi ( 20 °C)
form
liquid
reaction suitability
reagent type: catalyst
core: titanium
concentration
0.95-1.10 M NaOH (titration), 1.0 M in methylene chloride
density
1.365 g/mL at 25 °C
Quality Level
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General description
氯化钛参与了芳香醛与甲基乙烯基酮的 Baylis-Hillman 反应。使用 pH 值为 2.5 至 6.0 的 TiCl 4 中性溶液(通过添加氧化镁作为基础制备)合成纳米二氧化钛。
Application
通过改良的 Bouveault 反应活化吡咯烷,以改善转化为相应的 α-二甲胺。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system
supp_hazards
存储类别
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Denton, S.M. Wood, A.
Synlett, 55-55 (1999)
Charles Dylan Turner et al.
Organic letters, 14(18), 4970-4973 (2012-09-08)
The Ti(IV)-catalyzed Ugi condensation of α-amino acids with electron-rich aromatic aldehydes performs adequately even with sterically demanding α-amino carboxylate salts. The reaction occurs diastereoselectively, in some cases with virtually complete diastereoselectivity. A stereochemical rationale for the reaction is proposed.
Kun Wang et al.
The oncologist, 20(3), 263-269 (2015-02-07)
The TERT promoter and FGFR3 gene mutations are two of the most common genetic events in urothelial bladder cancer (UBC), and these mutation assays in patient urine have been shown to be promising biomarkers for UBC diagnosis and surveillance. These
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