蒸汽压
24.09 psi ( 55 °C)
6.93 psi ( 20 °C)
质量水平
表单
liquid
反应适用性
reagent type: catalyst
core: titanium
浓度
0.95-1.10 M NaOH (titration)
1.0 M in methylene chloride
密度
1.365 g/mL at 25 °C
SMILES字符串
Cl[Ti](Cl)(Cl)Cl
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
正在寻找类似产品? 访问 产品对比指南
一般描述
氯化钛参与了芳香醛与甲基乙烯基酮的 Baylis-Hillman 反应。使用 pH 值为 2.5 至 6.0 的 TiCl 4 中性溶液（通过添加氧化镁作为基础制备）合成纳米二氧化钛。
应用
通过改良的 Bouveault 反应活化吡咯烷，以改善转化为相应的 α-二甲胺。
警示用语：
Danger
危险分类
Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Central nervous system
补充剂危害
储存分类代码
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
此项目有
Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Denton, S.M. Wood, A.
Synlett, 55-55 (1999)
Charles Dylan Turner et al.
Organic letters, 14(18), 4970-4973 (2012-09-08)
The Ti(IV)-catalyzed Ugi condensation of α-amino acids with electron-rich aromatic aldehydes performs adequately even with sterically demanding α-amino carboxylate salts. The reaction occurs diastereoselectively, in some cases with virtually complete diastereoselectivity. A stereochemical rationale for the reaction is proposed.
Kun Wang et al.
The oncologist, 20(3), 263-269 (2015-02-07)
The TERT promoter and FGFR3 gene mutations are two of the most common genetic events in urothelial bladder cancer (UBC), and these mutation assays in patient urine have been shown to be promising biomarkers for UBC diagnosis and surveillance. These
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持