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33214

乙酸酐

ACS reagent grade, ≥99% (GC), puriss. p.a., reag. ISO, reag. Ph. Eur.

别名:

Acetanhydride, Acetic acid anhydride, Acetyl acetate, Acetyl anhydride, Ethanoic anhydride

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关于此项目

线性分子式:
(CH3CO)2O
化学文摘社编号:
分子量:
102.09
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-564-8
MDL number:
Beilstein/REAXYS Number:
385737
Assay:
≥99% (GC)
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产品名称

乙酸酐, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99% (GC)

Quality Segment

agency

USP/NF, reag. ISO, reag. Ph. Eur.

vapor density

3.5 (vs air)

vapor pressure

10 mmHg ( 36 °C), 4 mmHg ( 20 °C)

grade

ACS reagent, puriss. p.a.

assay

≥99% (GC)

autoignition temp.

629 °F

expl. lim.

10.3 %

impurities

≤0.003% non-volatile matter, ≤0.01% KMnO4 red. matter (as O)

refractive index

n20/D 1.390 (lit.)

bp

138-140 °C (lit.)

mp

−73 °C (lit.)

density

1.08 g/mL (lit.)

anion traces

chloride (Cl-): ≤2 mg/kg, phosphate (PO43-): ≤10 mg/kg, sulfate (SO42-): ≤5 mg/kg

cation traces

Al: ≤0.5 mg/kg, B: ≤0.02 mg/kg, Ba: ≤0.1 mg/kg, Ca: ≤0.5 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.05 mg/kg, Cu: ≤0.02 mg/kg, Fe: ≤0.1 mg/kg, Mg: ≤0.1 mg/kg, Mn: ≤0.02 mg/kg, Ni: ≤0.02 mg/kg, Pb: ≤0.1 mg/kg, Sn: ≤0.1 mg/kg, Zn: ≤0.2 mg/kg

suitability

passes test for reaction against H2SO4

SMILES string

CC(=O)OC(C)=O

InChI

1S/C4H6O3/c1-3(5)7-4(2)6/h1-2H3

InChI key

WFDIJRYMOXRFFG-UHFFFAOYSA-N

General description

Acetic anhydride is a colorless liquid. On dissolution in water, it undergoes solvolysis to afford acetic acid. It is widely employed as acetylation reagent for the acetylation of various alcohols. Wacher process (starting reagent + a ketene) and Knapsack process (starting reagent = acetaldehyde) have been reported for the industrial preparation of acetic anhydride. It is employed as solvent for various organic reactions.

Application

  • Modification of Quinoa Starches: Acetic anhydride is used to modify the structure of starch molecules, discussing its implications on improving bread quality and food processing (Wang et al., 2024).

Other Notes

The article number 33214-4X2.5L will be discontinued. Please order the single bottle 33214-2.5L which is physically identical with the same exact specifications.
The article number 33214-4X2.5L-M will be discontinued. Please order the single bottle 33214-2.5L-M which is physically identical with the same exact specifications.
The article number 33214-6X1L will be discontinued. Please order the single bottle 33214-1L which is physically identical with the same exact specifications.
The article number 33214-6X1L-M will be discontinued. Please order the single bottle 33214-1L-M which is physically identical with the same exact specifications.


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警示词

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

存储类别

3 - Flammable liquids

闪点 (F)

120.2 °F - closed cup

闪点 (°C)

49 °C - closed cup



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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