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Merck
CN

33427

2,4-TDI

analytical standard

别名:

甲苯-2,4-二异氰酸酯, 2,4-二异氰酸基甲苯, 2,4-二异氰酸甲苯酯, 4-甲基-间亚苯基二异氰酸酯

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关于此项目

经验公式(希尔记法):
C9H6N2O2
化学文摘社编号:
分子量:
174.16
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
209-544-5
Beilstein/REAXYS Number:
744602
MDL number:
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产品名称

2,4-TDI, analytical standard

InChI key

DVKJHBMWWAPEIU-UHFFFAOYSA-N

InChI

1S/C9H6N2O2/c1-7-2-3-8(10-5-12)4-9(7)11-6-13/h2-4H,1H3

SMILES string

Cc1ccc(cc1N=C=O)N=C=O

grade

analytical standard

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

bp

124-126 °C/18 mmHg (lit.)
251 °C (lit.)

mp

19.5-21.5 °C (lit.)

density

1.22 g/mL at 20 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

room temp

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General description

2,4-TDI是二异氰酸酯类环境污染物。它在商业上可作为油漆、涂料、弹性体、聚氨酯泡沫、漆包线漆的起始材料。
这种物质被列入EU第10/2011号法规中用于与食品接触的塑料的正面清单。

10/2011号清单所列全部化合物的标准物质见此

Application

2,4-TDI可作为分析参考标准品,用于通过色谱技术定量分析气相和生物流体中的分析物。

pictograms

Skull and crossbonesHealth hazard

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Aquatic Chronic 3 - Carc. 2 - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

269.6 °F - closed cup

flash_point_c

132 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Biological monitoring of occupational exposure to toluene diisocyanate: measurement of toluenediamine in hydrolysed urine and plasma by gas chromatography-mass spectrometry
Persson P, et al.
Occupational and Environmental Medicine, 50(12), 1111-1118 (1993)
Determination of gas-phase produced ethyl parathion and toluene 2, 4-diisocyanate by ion mobility spectrometry, gas chromatography and liquid chromatography
Nousiainen M, et al.
Talanta, 72(3), 984-990 (2007)
Norman Mangner et al.
JACC. Cardiovascular imaging, 7(12), 1198-1205 (2014-10-13)
The aim of our study was to assess geometric and functional changes of the heart in obese compared with nonobese children and adolescents. Obesity in children and adolescents has increased over the past decades and is considered a strong risk
Tatiana Kuznetsova et al.
American journal of hypertension, 28(4), 535-545 (2014-09-23)
The cardio-renal interaction occurs via hemodynamic and humoral factors. Noninvasive assessment of renal hemodynamics is currently possible by assessment of renal resistive index (RRI) derived from intrarenal Doppler arterial waveforms as ((peak systolic velocity - end-diastolic velocity)/peak systolic velocity). Limited
Olov Collste et al.
Journal of cardiac failure, 20(12), 968-972 (2014-10-01)
Our objective was to investigate whether dobutamine stress echocardiography (DSE) could induce abnormal cardiac function in takotsubo stress cardiomyopathy (TSC) patients in a stable condition after the acute attack. This was a case-control study and a substudy of the Stockholm

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