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Merck
CN

56845

L-(+)-赤藓酮糖

≥75% (HPLC)

别名:

S-1,3,4-三羟基-2-丁酮, L-2-丙三氧基-2-酮丁糖

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关于此项目

经验公式(希尔记法):
C4H8O4
化学文摘社编号:
分子量:
120.10
NACRES:
NA.25
PubChem Substance ID:
UNSPSC Code:
12352201
MDL number:
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InChI key

UQPHVQVXLPRNCX-VKHMYHEASA-N

SMILES string

OC[C@H](O)C(=O)CO

InChI

1S/C4H8O4/c5-1-3(7)4(8)2-6/h3,5-7H,1-2H2/t3-/m0/s1

assay

≥75% (HPLC)

form

liquid

optical activity

[α]/D 12.0±2.0°, c = 2 in H2O (24 h)

impurities

≤23% water

color

light yellow

storage temp.

room temp

Quality Level

Application

L-(+)-赤藓糖在化妆品工业中可用作鞣剂,并在醛醇缩合反应有机合成中用作手性乙基酮的来源。

Other Notes

为了全面了解我们针对客户研究提供的各种单糖产品,建议您访问我们的碳水化合物分类页面。

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves

法规信息

涉药品监管产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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G L Simpson et al.
Biochimica et biophysica acta, 1501(1), 12-24 (2000-03-23)
The degradation of L-ascorbate (AsA) and its primary oxidation products, L-dehydroascorbate (DHA) and 2,3-L-diketogulonate (2, 3-DKG) were studied under physiological conditions. Analysis determined that L-erythrulose (ERU) and oxalate were the primary degradation products of ASA regardless of which compound was
Santiago Díaz-Oltra et al.
The Journal of organic chemistry, 70(20), 8130-8139 (2005-11-10)
[Chemical reaction: See text] Both matched and mismatched diastereoselections have been observed in the aldol reactions of a range of chiral aldehydes with the dicyclohexylboron enolate of a chiral ethyl ketone related to L-erythrulose. As was previously observed in the
Jörn Voss et al.
Microbiology (Reading, England), 156(Pt 6), 1890-1899 (2010-03-13)
The growth of Gluconobacter oxydans DSM 7145 on meso-erythritol is characterized by two stages: in the first stage, meso-erythritol is oxidized almost stoichiometrically to L-erythrulose according to the Bertrand-Hudson rule. The second phase is distinguished from the first phase by
Maria-José Henríquez et al.
Biotechnology progress, 36(1), e2893-e2893 (2019-08-20)
Whole cell biocatalysis is an ideal tool for biotransformations that demand enzyme regeneration or robustness to fluctuating pH, osmolarity and biocontaminant load in feedstocks. The methylotrophic yeast Komagataella phaffii is an attractive alternative to Escherichia coli for whole cell biocatalysis
J Alberto Marco et al.
The Journal of organic chemistry, 68(22), 8577-8582 (2003-10-25)
Both matched and mismatched diastereoselections have been observed in aldol reactions of the B,B-dicyclohexylboron enolate of a protected l-erythrulose derivative with a range of chiral aldehydes. The stereochemical outcome of reactions with alpha-methyl aldehydes can be adequately explained within the

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