M0285
甲基-β- D -吡喃半乳糖苷
别名:
甲基 β- D -半乳糖苷
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关于此项目
经验公式（希尔记法）:
C7H14O6
化学文摘社编号:
分子量:
194.18
UNSPSC Code:
12352201
NACRES:
NA.25
PubChem Substance ID:
EC Number:
217-361-7
Beilstein/REAXYS Number:
81569
MDL number:
InChI key
HOVAGTYPODGVJG-VOQCIKJUSA-N
InChI
1S/C7H14O6/c1-12-7-6(11)5(10)4(9)3(2-8)13-7/h3-11H,2H2,1H3/t3-,4+,5+,6-,7-/m1/s1
SMILES string
CO[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O
biological source
synthetic
assay
≥98% (GC)
form
powder
technique(s)
gas chromatography (GC): suitable
color
white to faint yellow
mp
176-179 °C
solubility
water: 50 mg/mL, clear, colorless
storage temp.
2-8°C
Quality Level
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存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
涉药品监管产品
此项目有
Feng Yang et al.
Carbohydrate research, 337(6), 485-491 (2002-03-14)
Oligosaccharide derivatives from sanqi, a Chinese herbal medicine derived from Panax notoginseng, methyl beta-D-galactopyranosyl-(1-->3)-[alpha-L-arabinofuranosyl-(1-->6)]-alpha-D-galactopyranoside, diosgenyl beta-D-galactopyranosyl-(1-->3)-[alpha-L-arabinofuranosyl-(1-->6)]-alpha-D-galactopyranoside, and methyl beta-D-galactopyranosyl-(1-->3)-[alpha-L-arabinofuranosyl-(1-->6)]-alpha-D-galactopyranosyl-(1-->4)-beta-D-galactopyranosyl-(1-->3)-[alpha-L-arabinofuranosyl-(1-->6)]-alpha-D-galactopyranoside, were synthesized under standard glycosylation conditions. An unexpected alpha-(1-->4) linkage was formed predominantly in the presence of neighboring participation group during
M E Winkler et al.
Journal of inorganic biochemistry, 14(3), 223-235 (1981-06-01)
Alcohol substrate binding to the copper-containing enzyme galactose oxidase (GOase) has been studied by kinetic competition against cyanide and fluoride, 13C nmr relaxation, and esr competition experiments. The 13C nmr spectra of the substrate beta-O-methyl-D-galactopyranoside (beta-O-me-gal) show no apparent paramagnetic
María del Carmen Fernández-Alonso et al.
Journal of the American Chemical Society, 127(20), 7379-7386 (2005-05-19)
The existence of stabilizing carbohydrate-aromatic interactions is demonstrated from both the theoretical and experimental viewpoints. The geometry of experimentally based galactose-lectin complexes has been properly accounted for by using a MP2/6-31G(d,p) level of theory and by considering a counterpoise correction
Peter Capek
Carbohydrate research, 343(8), 1390-1393 (2008-04-25)
An arabinogalactan with a high content of 3-O-methyl-D-galactose residues has been isolated from the aerial parts of sage (Salvia officinalis L.). Structural studies of the polymer indicated a beta-1,6-D-galactopyranose backbone in which at least one-third of D-galactopyranosyl residues carries methoxyl
Satoru Takahashi et al.
Epilepsy research, 80(1), 18-22 (2008-05-06)
Glucose transporter 1 (GLUT1) deficiency syndrome is caused by a deficit in glucose transport to the brain during the pre- and postnatal periods. Here, we report two cases of GLUT1 deficiency syndrome diagnosed on the basis of clinical features, reduced
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