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Supelco

Permethrin

PESTANAL®, analytical standard

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Empirical Formula (Hill Notation):
C21H20Cl2O3
CAS Number:
52645-53-1
Molecular Weight:
391.29
Beilstein:
5765325
EC Number:
258-067-9
MDL number:
MFCD00041809
PubChem Substance ID:
329756835
NACRES:
NA.24

grade

analytical standard

Quality Level

100

description

mixture of cis and trans isomers

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CC1(C)C(\C=C(/Cl)Cl)C1C(=O)OCc2cccc(Oc3ccccc3)c2

InChI

1S/C21H20Cl2O3/c1-21(2)17(12-18(22)23)19(21)20(24)25-13-14-7-6-10-16(11-14)26-15-8-4-3-5-9-15/h3-12,17,19H,13H2,1-2H3

InChI key

RLLPVAHGXHCWKJ-UHFFFAOYSA-N

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General description

Permethrin belongs to the pyrethroid class of insecticides.

Application

Permethrin may be used as an analytical reference standard for the determination of permethrin in:
  • Virgin olive oil samples by liquid-liquid extraction (LLE) or low-temperature precipitation followed by Sep-Pak alumina-N column clean-up and analysis using gas chromatography equipped with electron capture detector (GC-ECD).
  • Whole blood samples by electron ionization GC coupled to mass spectrometry (MS) operating in selected ion monitoring (SIM) mode.
  • Tomato sample extracts by high performance liquid chromatography (HPLC) with post-column photoderivatization and acetonitrile chemiluminescence based detection.
  • Water samples by ultrasound-assisted emulsification-extraction (UAEE) and GC-negative ion chemical ionization (NCI) MS.
  • Apple juice samples by matrix solid-phase dispersion (MSPD) and GC-MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Analysis Note

appearance: Yellow to brownish liquid, might be crystallized at room temperature

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302 + H332 - H317 - H410

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

农药列管产品

Certificates of Analysis (COA)

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T1503
Product Number
-
25G
Pack Size/Quantity

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705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

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Lot and Batch Numbers can be found on a product's label following the words 'Lot' or 'Batch'.

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  • For a lot number such as TO09019TO, enter it as 09019TO (without the first two letters 'TO').

  • For a lot number with a filling-code such as 05427ES-021, enter it as 05427ES (without the filling-code '-021').

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Determination of nine pyrethroid insecticides by high-performance liquid chromatography with post-column photoderivatization and detection based on acetonitrile chemiluminescence.
Galera MM, et al.
Journal of Chromatography A, 1113(1-2), 191-197 (2006)
Electron ionization gas chromatography-mass spectrometric determination of residues of thirteen pyrethroid insecticides in whole blood.
Ramesh A and Ravi PE
Journal of Chromatography. B, Biomedical Sciences and Applications, 802(2), 371-376 (2004)
Determination of residues of endosulfan and five pyrethroid insecticides in virgin olive oil using gas chromatography with electron-capture detection.
Lentza-Rizos Ch, et al.
Journal of Chromatography A, 921(2), 297-304 (2001)
A rapid and sensitive analytical method for the determination of 14 pyrethroids in water samples.
Feo ML, et al.
Journal of Chromatography A, 1217(15), 2248-2253 (2010)
Nigel B Perry et al.
Journal of natural products, 71(2), 258-261 (2008-02-01)
Clavigerin A ( 1) was isolated from the New Zealand liverwort Lepidolaena clavigera and shown to be a polyoxygenated bergamotane sesquiterpene with an unusual ring system. L. clavigera shows infraspecific variation, since 1 was the only clavigerin detected in a
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