07404
Jone′s reagent
~2% CrO3 basis
Synonym(s):
Chromium trioxide solution in sulfuric acid, Sulfuric acid-chromium trioxide mixture
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About This Item
reaction suitability
reagent type: oxidant
concentration
~2% (CrO3)
SMILES string
O=[Cr](=O)=O.OS(O)(=O)=O
InChI
1S/Cr.H2O4S.3O/c;1-5(2,3)4;;;/h;(H2,1,2,3,4);;;
InChI key
HNPXHFOTGAXAJY-UHFFFAOYSA-N
Application
Reactant for:
- Oxidation of oximes to carbonyl compounds
- Oxidation of benzoins to benzils
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Carc. 1B - Eye Dam. 1 - Met. Corr. 1 - Muta. 1B - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1A - Skin Sens. 1 - STOT RE 2 Inhalation
target_organs
Cardio-vascular system
Storage Class
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Oxidation of benzoins to benzils with the Jones' reagent supported on graphite
Lou, J.-D.; et al.
Oxidation Communications, 33, 550-554 (2010)
Efficient oxidative conversion of oximes to the corresponding carbonyl compounds with the Jones reagent supported on graphite under heterogeneous conditions
Lou, J.-D.; et al.
Oxidation Communications, 34, 604-609 (2011)