102938
2-Acetyl-5-norbornene, mixture of endo and exo
technical grade
Synonym(s):
Methyl 5-norbornen-2-yl ketone
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About This Item
Empirical Formula (Hill Notation):
C9H12O
CAS Number:
Molecular Weight:
136.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
225-767-0
MDL number:
Product Name
2-Acetyl-5-norbornene, mixture of endo and exo, technical grade
InChI key
NIMLCWCLVJRPFY-WGTSGOJVSA-N
InChI
1S/C9H12O/c1-6(10)9-5-7-2-3-8(9)4-7/h2-3,7-9H,4-5H2,1H3/t7-,8+,9?/m1/s1
SMILES string
CC(=O)C1C[C@H]2C[C@@H]1C=C2
grade
technical grade
refractive index
n20/D 1.484 (lit.)
bp
84-86 °C/18 mmHg (lit.)
density
1.005 g/mL at 25 °C (lit.)
functional group
ketone
Application
2-Acetyl-5-norbornene was used in the synthesis of the 2-acetylnorbornyl isothiocyanates: exo-2-acetyl-exo-6-isothiocyanatonorbornane, endo-2-acetyl-exo-6-isothiocyanatonorbornane and exo-2-acetyl-exo-5-isothiocyanatonorbornane.
General description
2-Acetyl-5-norbornene, mixture of endo and exo is a colorless to light yellow liquid.
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Y Zhang et al.
Proceedings of the National Academy of Sciences of the United States of America, 91(8), 3147-3150 (1994-04-12)
Sulforaphane [1-isothiocyanato-4-(methyl-sulfinyl)butane] was recently isolated from one variety of broccoli as the major and very potent inducer of phase 2 detoxication enzymes in murine hepatoma cells in culture. Since phase 2 enzyme induction is often associated with reduced susceptibility of
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