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Merck
CN

104914

Dichloromethylvinylsilane

97%

Synonym(s):

Methylvinyldichlorosilane

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About This Item

Linear Formula:
H2C=CHSi(CH3)Cl2
CAS Number:
Molecular Weight:
141.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-710-3
Beilstein/REAXYS Number:
1740822
MDL number:
Assay:
97%
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vapor density

>1 (vs air)

Quality Level

assay

97%

refractive index

n20/D 1.430 (lit.)

bp

92 °C (lit.)

density

1.08 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C[Si](Cl)(Cl)C=C

InChI

1S/C3H6Cl2Si/c1-3-6(2,4)5/h3H,1H2,2H3

InChI key

YLJJAVFOBDSYAN-UHFFFAOYSA-N

General description

Dichloromethylvinylsilane reacts with dimethylsulphide borane to form organosilylborane, which further gets ammonolysized to form the polymer of the SiBCN.

Application

Dichloromethylvinylsilane was used as single molecular precursor for the deposition of β-SiC thin films and β -SiC nanowires by metalorganic chemical vapor deposition on bare Si 100 and Ni-coated Si 100 substrates. Dichloromethylvinylsilane was used in the synthesis and characterization of Tris(1-(dichloro(methyl)silyl)ethyl)borane,monomer.


signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2 - Skin Corr. 1B

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

38.1 °F - closed cup

flash_point_c

3.4 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Synthesis and Structure Characterization of Amorphous SiBCN Ceramic Precursors.
Yajing L and Yue Z.
Rare Metals Materials and Engineering, 40, 234-237 (2011)
Influence of the Precursor Cross-Linking Route on the Thermal Stability of Si- B- C- O Ceramics.
Ischenko V, et al.
Chemistry of Materials, 20(22), 7148-7156 (2008)
Growth of β-SiC nanowires and thin films by metalorganic chemical vapor deposition using dichloromethylvinylsilane.
Kang B-C, et al.
J. Vac. Sci. Technol. B, 23(4), 1722-1725 (2005)



Global Trade Item Number

SKUGTIN
104914-100G04061838344793
104914-500G04061837082566