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Merck
CN

106887

Ferrocenecarboxylic acid

97%

Synonym(s):

(Carboxycyclopentadienyl)cyclopentadienyliron, Carboxyferrocene, Carboxylferrocene, Cyclopentadienecarboxylic acid, Ferrocenoic acid

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About This Item

Empirical Formula (Hill Notation):
C11H10FeO2
CAS Number:
1271-42-7
Molecular Weight:
230.04
NACRES:
NA.22
PubChem Substance ID:
24846745
UNSPSC Code:
12352300
EC Number:
215-040-6
MDL number:
MFCD00001430

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InChI key

VUJLGCHOGQEAED-UHFFFAOYSA-N

InChI

1S/C6H5O2.C5H5.Fe/c7-6(8)5-3-1-2-4-5;1-2-4-5-3-1;/h1-4H,(H,7,8);1-5H;

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.OC(=O)[C]2[CH][CH][CH][CH]2

assay

97%

reaction suitability

core: iron, reagent type: catalyst

mp

210 °C (dec.) (lit.)

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General description

Papanicolaou is a widely used stain in cytopathology. It is a polychrome stain that has the ability to stain several constituents of cell differentially due to the presence of multiple dyes. Papanicolaou stain consists of a basic dye, haematoxylin that stains the nucleus and three acid dyes like light green, eosin and orange G that stain the cytoplasm.

Application

Used to esterify complex mixtures of phenols and alcohols for analysis by GCMS.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBC7558
04128TH
08404TH
15401KE
06325JW

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Color Atlas of Pulmonary Cytopathology (2012)
Decoration of cowpea mosaic virus with multiple, redox-active, organometallic complexes.
Nicole F Steinmetz et al.
Small (Weinheim an der Bergstrasse, Germany), 2(4), 530-533 (2006-12-29)
Shaoling Song et al.
The journal of physical chemistry. B, 114(35), 11689-11695 (2010-08-17)
Poly(4-vinylpyridine) (P4VP) films were electropolymerized on a pyrolytic graphite (PG) electrode surface. The cyclic voltammetric (CV) response of ferrocenedicarboxylic acid (Fc(COOH)(2)) at P4VP film electrodes was very sensitive to the pH and perchlorate (ClO(4)(-)) concentration in testing solutions. Fc(COOH)(2) was
Ewa Nazaruk et al.
Bioelectrochemistry (Amsterdam, Netherlands), 71(1), 8-14 (2007-02-10)
The monoolein-based liquid crystalline cubic phase was used as the matrix to incorporate redox enzymes--glucose (GOx), pyranose (PyOx) oxidases and laccase. Thin layer of the cubic phase embedding GOx or PyOx activated glucose oxidation in the presence and absence of
Georg Diehl et al.
Journal of chromatography. A, 974(1-2), 103-109 (2002-12-03)
Rapid liquid chromatographic separations of ferrocenecarboxylic esters of various alcohols and phenols have been achieved on reversed-phase columns of 20 mm length. After separation, the ferrocene derivatives are oxidized electrochemically under formation of the charged ferrocinium species, which are easily
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