108189
Tris(hydroxymethyl)nitromethane
98%
Synonym(s):
2-Hydroxymethyl-2-nitro-1,3-propanediol
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About This Item
Linear Formula:
NO2C(CH2OH)3
CAS Number:
Molecular Weight:
151.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-769-5
Beilstein/REAXYS Number:
1768985
MDL number:
Assay:
98%
Form:
solid
assay
98%
form
solid
mp
160 °C (dec.) (lit.)
solubility
H2O: soluble 220g/100ml at 20 °C, alcohols: freely soluble, benzene: very slightly soluble, hydrocarbons: very slightly soluble
functional group
amine, hydroxyl, nitro
SMILES string
OCC(CO)(CO)[N+]([O-])=O
InChI
1S/C4H9NO5/c6-1-4(2-7,3-8)5(9)10/h6-8H,1-3H2
InChI key
OLQJQHSAWMFDJE-UHFFFAOYSA-N
General description
Tris(hydroxymethyl)nitromethane undergoes crosslinking with hexamethylene diisocyanate to form monolithic energetic gels. It is an effective hardener for variety of tannin-based adhesives.
Preparation Note
220 g of Tris(hydroxymethyl)nitromethane dissolves in 100 ml of water at 20°C.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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M H Robertson et al.
Archives of dermatology, 118(12), 997-1002 (1982-12-01)
Two machinists were seen whose chronic hand dermatitis was explained by allergic sensitivity to a biocide, Tris Nitro (2-[hydroxymethyl]-2-nitro-1,3-propanediol), which was added to their metalworking fluids (cutting oils) to prevent rancidity. The cause of the men's difficulty was first suspected
A no-aldehyde emission hardener for tannin-based wood adhesives for exterior panels
Trosa A and Pizzi A.
European Journal of Wood and Wood Products, 59(4), 266-271 (2001)
Nanostructured Energetic Composites of CL-20 and Binders Synthesized by Sol Gel Methods.
Li J and Brill TB.
Propellants, Explosives, Pyrotechnics, 31(1), 61-69 (2006)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 8036460100 | 04022536382999 |
| 471224-4X2.5L | 04061832359625 |
| 471224-100ML | 04061832359595 |
| 471224-500ML | 04061832359632 |
| 110019-100ML | 04061837367977 |
| 110019-500ML | 04061837367991 |
| 38290-1L-F | 04061831963403 |
| 38290-250ML-F | 04061831963410 |
| 8036460010 | 04027269250461 |
| 8036461000 | 04022536383002 |
| 8036461001 | 04027269569037 |
| 8036462500 | 04022536383019 |
| 8036469020 | 04022536753508 |
| 386464-4X100ML | 04061838127013 |
| 386464-1L | 04061838127006 |