108871
4-Chloro-o-phenylenediamine
97%
Synonym(s):
4-Chloro-1,2-diaminobenzene
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About This Item
Linear Formula:
ClC6H3(NH2)2
CAS Number:
Molecular Weight:
142.59
Beilstein:
508472
EC Number:
MDL number:
UNSPSC Code:
12162002
eCl@ss:
39030501
PubChem Substance ID:
NACRES:
NA.23
Quality Level
Assay
97%
mp
70-73 °C (lit.)
SMILES string
Nc1ccc(Cl)cc1N
InChI
1S/C6H7ClN2/c7-4-1-2-5(8)6(9)3-4/h1-3H,8-9H2
InChI key
BXIXXXYDDJVHDL-UHFFFAOYSA-N
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Application
Undergoes cyclizations and cyclocondensations to form benzimidazoles.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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The Journal of Organic Chemistry, 58, 7016-7016 (1993)
Synthesis, 446-446 (1992)
4-Chloro-o-phenylenediamine.
Report on carcinogens : carcinogen profiles, 12, 101-102 (2011-08-19)
Oz Malkesman et al.
The international journal of neuropsychopharmacology, 15(8), 1135-1148 (2011-09-13)
Research suggests that dysfunctional glutamatergic signalling may contribute to depression, a debilitating mood disorder affecting millions of individuals worldwide. Ketamine, a N-methyl-D-aspartate (NMDA) receptor antagonist, exerts rapid antidepressant effects in approximately 70% of patients. Glutamate evokes the release of D-serine
Hiroshi Suzuki et al.
Mutation research, 583(2), 133-145 (2005-05-19)
We conducted simultaneous liver and peripheral blood micronucleus assays in young rats with seven rodent hepatocarcinogens-4,4'-methylenedianiline (MDA), quinoline, o-toluidine, 4-chloro-o-phenylenediamine (CPDA), dimethylnitrosamine (DMN), p-dimethylaminoazobenzene (DAB), and di(2-ethylhexyl)phthalate (DEHP)-and two mutagenic chemicals-kojic acid and methylmethanesulfonate (MMS). Quinoline, DMN, and DAB were
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