10906
Chloroacetaldehyde dimethyl acetal
Wacker Chemie AG, ≥99.0% (GC)
Synonym(s):
CADMA, 2-Chloro-1,1-dimethoxyethane, Dimethyl chloroacetal
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About This Item
Linear Formula:
ClCH2CH(OCH3)2
CAS Number:
Molecular Weight:
124.57
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-624-0
Beilstein/REAXYS Number:
1733700
MDL number:
Assay:
≥99.0% (GC)
Quality Level
assay
≥99.0% (GC)
manufacturer/tradename
Wacker Chemie AG
refractive index
n20/D 1.415 (lit.)
bp
128-130 °C (lit.)
density
1.094 g/mL at 25 °C (lit.)
SMILES string
COC(CCl)OC
InChI
1S/C4H9ClO2/c1-6-4(3-5)7-2/h4H,3H2,1-2H3
InChI key
CRZJPEIBPQWDGJ-UHFFFAOYSA-N
General description
Chloroacetaldehyde dimethyl acetal is a clear, colorless liquid. It reacts with hydroxythiol to form hydroxy acetal.
Application
Chloroacetaldehyde dimethyl acetal was used to investigate the enzymes used for activation and transformation of vinyl chloride. It was also used for introducing O-(2,2-dimethoxyethyl) groups into amylose, dextran, and a linear (1→3)-β-D-glucan. Chloroacetaldehyde dimethyl acetal was utilised in the synthesis of ethoxyacetylide.
Chloroacetaldehyde dimethyl acetal can be used as a reactant to synthesize:
- 2-(chloromethyl)-4,7-dethyl-1,3-dioxepane
- 2-(chloromethyl)-5,6-benzo-1,3-dioxepane
- ketene dimethyl acetal
Other Notes
prices for bulk quantities on request
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Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 3
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
84.2 °F - closed cup
flash_point_c
29 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Coupling of polysaccharides activated by means of chloroacetaldehyde dimethyl acetal to amines or proteins by reductive amination.
B?gwald J, et al.
Carbohydrate Research, 148(1), 101-107 (1986)
Activation of vinyl chloride to covalently bound metabolites: roles of 2-chloroethylene oxide and 2-chloroacetaldehyde.
F P Guengerich et al.
Biochemistry, 18(23), 5177-5182 (1979-11-13)
Recent trends in the synthesis of carbazoles: an update.
Tetrahedron, 68(31), 6099-6121 (2012)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| V800101-500G | 04061832599229 |
| V800100-6X500G | 04061832760889 |
| 1020590500 | 04022536028439 |
| 1020699025 | 04022536028729 |
| 1017071000 | 04027269077730 |
| 1020590050 | 04022536028422 |
| 1020669050 | 04022536028620 |
| 1024100050 | 04022536687643 |
| PHR1326-5G | 04061835233632 |
| NIST2193B | 04065266888737 |
| 795445-100G | 04061832955032 |
| CX0120-5 | 04061839417229 |
| 1086403-1G | 04061838686244 |
| 202932-25G | 04061838765413 |
| 202932-100G | 04061838765406 |
| 202932-5G | 04061838765420 |
| 21067-25G | 04061835560059 |
| 21069-1KG | 04061838771438 |
| 21061-50G-F | 04061838771377 |
| 239216-1KG | 04061838787361 |
| 239216-100G | 04061838787354 |
| 239216-500G | 04061838787378 |
| 481807-25G | 04061832388809 |