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110485

trans-5-Decene

Name: <I>trans</I>-5-Decene
Brand: ALDRICH

98%

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About This Item

Linear Formula:

CH₃(CH₂)₃CH=CH(CH₂)₃CH₃

CAS Number:

7433-56-9

Molecular Weight:

140.27

NACRES:

NA.22

PubChem Substance ID:

24846988

UNSPSC Code:

12352100

EC Number:

231-080-7

MDL number:

MFCD00009508

Assay:

98%

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Properties

Quality Level

100

assay

98%

refractive index

n20/D 1.424 (lit.)

bp

170 °C/750 mmHg (lit.)

density

0.74 g/mL at 25 °C (lit.)

SMILES string

[H]\C(CCCC)=C(\[H])CCCC

InChI

1S/C10H20/c1-3-5-7-9-10-8-6-4-2/h9-10H,3-8H2,1-2H3/b10-9+

InChI key

UURSXESKOOOTOV-MDZDMXLPSA-N

Description

Application

trans-5-Decene has been used to characterize the effect of cyclization and size on the stability of Criegee intermediates formed in ozonolysis. It has been added to phenoxathiin cation radical in acetonitrile solution to form bis(10-phenoxathiiniumyl) alkane adducts.

pictograms

GHS02,GHS07

signalword

Warning

hcodes

H226,H315,H319,H335

pcodes

P210 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

114.8 °F - closed cup

flash_point_c

46 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Thermodynamics-based modelling of gas chromatography separations across column geometries and systems, including the prediction of peak widths.

Keisean A J M Stevenson et al.

Journal of separation science, 42(11), 2013-2022 (2019-04-10)

Thermodynamics-based models have been demonstrated to be useful for predicting retention time and peak widths in gas chromatography and two-dimensional gas chromatography separations. However, the collection of data to train the models can be time consuming, which lessens the practical

Pressure dependence of stabilized Criegee intermediate formation from a sequence of alkenes.

Greg T Drozd et al.

The journal of physical chemistry. A, 115(17), 4381-4387 (2011-04-12)

Ozonolysis is a key reaction in atmospheric chemistry, although important details of the behavior of the ozonolysis intermediates are not known. The key intermediate in ozonolysis, the Criegee intermeiate (CI), is known to quickly isomerize, with the favored unimolecular pathway

Addition of the phenoxathiin cation radical to alkenes and nonconjugated dienes. Formation of (E)- and (Z)-(10-phenoxathiiniumyl)alkenes and (E)- and (Z)-(10-phenoxathiiniumyl)dienes on basic alumina.

Bing-Jun Zhao et al.

The Journal of organic chemistry, 72(16), 6154-6161 (2007-07-03)

Addition of phenoxathiin cation radical (PO*+) to acyclic alkenes in acetonitrile (MeCN) solution occurred stereospecifically to form bis(10-phenoxathiiniumyl)alkane adducts. Stereospecific trans addition is ascribed to the intermediacy of an episulfonium cation radical. The alkenes used were cis- and trans-2-butene, cis-

Global Trade Item Number

SKU	GTIN
CBR02059-1G	04061825140209
110485-5G	04061837322525