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110779

Ethylidenecyclohexane

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About This Item

Linear Formula:
C6H10(=CHCH3)
CAS Number:
1003-64-1
Molecular Weight:
110.20
NACRES:
NA.22
PubChem Substance ID:
24847003
UNSPSC Code:
12352100
EC Number:
213-711-8
MDL number:
MFCD00001662
Assay:
99%
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Quality Level

100

assay

99%

refractive index

n20/D 1.462 (lit.)

bp

136 °C (lit.)

density

0.822 g/mL at 25 °C (lit.)

SMILES string

C\C=C1\CCCCC1

InChI

1S/C8H14/c1-2-8-6-4-3-5-7-8/h2H,3-7H2,1H3

InChI key

BPBOWYWUOUJKLO-UHFFFAOYSA-N

General description

Ethylidenecyclohexane is oxidized by purified ethylbenzene dehydrogenase.

Application

Ethylidenecyclohexane has been used as a substrate in the Lewis-acid catalyzed reactions of azodicarboxylates with different alkenes.

pictograms

Flame
GHS02

signalword

Warning

hcodes

H226

Hazard Classifications

Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

75.2 °F - closed cup

flash_point_c

24 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV1421
MKCN1644
MKCL7085
MKCL5594
MKBH6738V

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Pompiliu S Aburel et al.
Organic & biomolecular chemistry, 3(12), 2344-2349 (2005-07-13)
Lewis acids such as Cu(OTf)(2), Zn(OTf)(2), Yb(OTf)(3) and Nd(OTf)(3) catalyze the aza-ene reaction of alkenes with azodicarboxylates, giving the allylic amination adducts. The use of bis(2,2,2-trichloroethyl)azodicarboxylate as the amination reagent and Cu(OTf)(2) and Yb(OTf)(3) as the catalysts gave the aza-ene
H A Johnson et al.
Journal of bacteriology, 183(15), 4536-4542 (2001-07-10)
The first step in anaerobic ethylbenzene mineralization in denitrifying Azoarcus sp. strain EB1 is the oxidation of ethylbenzene to (S)-(-)-1-phenylethanol. Ethylbenzene dehydrogenase, which catalyzes this reaction, is a unique enzyme in that it mediates the stereoselective hydroxylation of an aromatic

Global Trade Item Number

SKUGTIN
110779-10G04061837322556