110779
Ethylidenecyclohexane
99%
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About This Item
Linear Formula:
C6H10(=CHCH3)
CAS Number:
Molecular Weight:
110.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
213-711-8
MDL number:
Assay:
99%
Product Name
Ethylidenecyclohexane, 99%
InChI key
BPBOWYWUOUJKLO-UHFFFAOYSA-N
InChI
1S/C8H14/c1-2-8-6-4-3-5-7-8/h2H,3-7H2,1H3
SMILES string
C\C=C1\CCCCC1
assay
99%
refractive index
n20/D 1.462 (lit.)
bp
136 °C (lit.)
density
0.822 g/mL at 25 °C (lit.)
Quality Level
Related Categories
Application
Ethylidenecyclohexane has been used as a substrate in the Lewis-acid catalyzed reactions of azodicarboxylates with different alkenes.
General description
Ethylidenecyclohexane is oxidized by purified ethylbenzene dehydrogenase.
signalword
Warning
hcodes
Hazard Classifications
Flam. Liq. 3
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
75.2 °F - closed cup
flash_point_c
24 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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H A Johnson et al.
Journal of bacteriology, 183(15), 4536-4542 (2001-07-10)
The first step in anaerobic ethylbenzene mineralization in denitrifying Azoarcus sp. strain EB1 is the oxidation of ethylbenzene to (S)-(-)-1-phenylethanol. Ethylbenzene dehydrogenase, which catalyzes this reaction, is a unique enzyme in that it mediates the stereoselective hydroxylation of an aromatic
Pompiliu S Aburel et al.
Organic & biomolecular chemistry, 3(12), 2344-2349 (2005-07-13)
Lewis acids such as Cu(OTf)(2), Zn(OTf)(2), Yb(OTf)(3) and Nd(OTf)(3) catalyze the aza-ene reaction of alkenes with azodicarboxylates, giving the allylic amination adducts. The use of bis(2,2,2-trichloroethyl)azodicarboxylate as the amination reagent and Cu(OTf)(2) and Yb(OTf)(3) as the catalysts gave the aza-ene
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