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Merck
CN

114685

4-Nitrophenylhydrazine

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About This Item

Linear Formula:
O2NC6H4NHNH2
CAS Number:
Molecular Weight:
153.14
EC Number:
202-824-8
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
608107
MDL number:
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InChI key

KMVPXBDOWDXXEN-UHFFFAOYSA-N

InChI

1S/C6H7N3O2/c7-8-5-1-3-6(4-2-5)9(10)11/h1-4,8H,7H2

SMILES string

NNc1ccc(cc1)[N+]([O-])=O

form

solid

contains

≥10% water as stabilizer

mp

156 °C (dec.) (lit.)

pictograms

Exploding BombExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Expl. 1.1 - Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

1 - Explosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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T Huque et al.
Comparative biochemistry and physiology. B, Comparative biochemistry, 86(1), 135-139 (1987-01-01)
The total plasmalogen content of lingual and other tissues was analyzed using the iodine-addition (Method 1), the p-nitrophenylhydrazone (Method 2), and the two-dimensional thin layer chromatography procedure (Method 3). Methods 1 and 2 were simple, rapid and reproducible, yielding values
N Nakamura et al.
The Journal of biological chemistry, 271(9), 4718-4724 (1996-03-01)
Resonance Raman spectroscopy is an excellent technique for providing structural information on the 2,4, 5-trihydroxyphenylalanine quinone (TPQ) cofactor in copper-containing amine oxidases. This technique has been used to investigate the copper- and O2-dependent biosynthesis of the TPQ cofactor in phenylethylamine
S R Carter et al.
Journal of inorganic biochemistry, 56(2), 127-141 (1994-11-01)
An improved purification scheme for an amine oxidase from equine plasma (EPAO), a nonruminant source, is described and the protein's active-site is characterized. EPAO is dimeric and contains one Type-2 Cu(II) ion per monomer. The EPAO Cu(II) site is spectroscopically
Minae Mure et al.
Journal of the American Chemical Society, 125(20), 6113-6125 (2003-06-06)
4-n-Butylamino-5-ethyl-1,2-benzoquinone (1(ox)) has been synthesized as a model compound for the LTQ (lysine tyrosyl quinone) cofactor of lysyl oxidase (LOX). At pH 7, 1(ox) has a lambda(max) at 504 nm and exists as a neutral o-quinone in contrast to a
R V Raju et al.
Journal of AOAC International, 77(3), 748-751 (1994-05-01)
Three spectrophotometric methods were developed for the microdetermination of decamethrin in insecticidal formulations and in water. The methods are based on the hydrolysis of decamethrin with methanolic KOH to 3-phenoxybenzaldehyde; condensation of the hydrolysis product with 2,4-dinitrophenylhydrazine (2,4-DNPH), 4-nitrophenyl-hydrazine (4-NPH)

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