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About This Item
Empirical Formula (Hill Notation):
C3H4LiNO2
CAS Number:
Molecular Weight:
93.01
UNSPSC Code:
12352005
PubChem Substance ID:
MDL number:
InChI
1S/C3H5NO2.Li/c5-3(6)2-1-4-2;/h2,4H,1H2,(H,5,6);/q;+1/p-1/t2-;/m0./s1
SMILES string
[Li+].[O-]C(=O)[C@@H]1CN1
InChI key
ZGQWDLXRNCMIHH-DKWTVANSSA-M
assay
≥97.0% (dried material, NT)
optical activity
[α]20/D −42±2°, c = 1% in H2O
impurities
~3% water
application(s)
peptide synthesis
Application
Lithium L-aziridine-2-carboxylate may be used as a chelate ligand to form complexes with transition metal salts.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Other Notes
Chiral building block; protected derivatives are used for the synthesis of various amino acids by ring-opening with nucleophiles
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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R.J. Parry et al.
Journal of the American Chemical Society, 107, 2512-2512 (1985)
K. Nakajima et al.
Bulletin of the Chemical Society of Japan, 56, 520-520 (1983)
Y. Kogami et al.
Bulletin of the Chemical Society of Japan, 60, 2963-2963 (1987)
Transition metal complexes of l-aziridine-carboxylate.
Hauck T, et al.
Inorgorganica Chimica Acta, 235(1-2), 391-396 (1995)
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