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Merck
CN

117498

1,2-Diaminopropane

99%

Synonym(s):

1,2-Propanediamine, Propylenediamine

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About This Item

Linear Formula:
CH3CH(NH2)CH2NH2
CAS Number:
78-90-0
Molecular Weight:
74.12
NACRES:
NA.22
PubChem Substance ID:
24847332
eCl@ss:
39030209
UNSPSC Code:
12352100
EC Number:
201-155-9
MDL number:
MFCD00008089
Beilstein/REAXYS Number:
605274

Key Documents

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Product Name

1,2-Diaminopropane, 99%

InChI

1S/C3H10N2/c1-3(5)2-4/h3H,2,4-5H2,1H3

InChI key

AOHJOMMDDJHIJH-UHFFFAOYSA-N

SMILES string

CC(N)CN

vapor density

2.6 (vs air)

vapor pressure

14 mmHg ( 20 °C)

assay

99%

autoignition temp.

680 °F

expl. lim.

11.1 %

refractive index

n20/D 1.446 (lit.)

bp

119-120 °C (lit.)

solubility

H2O: very soluble

density

0.87 g/mL at 25 °C (lit.)

functional group

amine

Quality Level

200

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Application

1,2-Diaminopropane was used as model precursor in the electron induced deposition of amorphous carbon nitride films.

General description

1,2-Diaminopropane undergoes condensation with salicylaldehyde and its derivatives to form Schiff base. It reacts with formaldehyde and hydrogen peroxide in aqueous acidic solution to give cage peroxide, 1,6-diaza-3,4,8,9-tetraoxa-11-methylbicyclo[4.4.2]dodecane.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3 - Resp. Sens. 1 - Skin Corr. 1A - Skin Sens. 1

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

93.2 °F - closed cup

flash_point_c

34 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ7224
MKCW0009
MKCW7326
0000145114
0000145114

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Chi Chen et al.
Molecules (Basel, Switzerland), 25(18) (2020-09-16)
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Substrate and reaction promiscuity is a remarkable property of some enzymes and facilitates the adaptation to new metabolic demands in the evolutionary process. Substrate promiscuity is also a basis for protein engineering for biocatalysis. However, molecular principles of enzyme promiscuity
Cage peroxides having planar bridgehead nitrogen atoms.
Edward JT, et al.
Canadian Journal of Chemistry, 77(5-6), 1057-1065 (1999)
Maryam Ghiyasiyan-Arani et al.
Scientific reports, 6, 25231-25231 (2016-05-05)
In this work, copper pyrovanadate (Cu3V2O7(OH)2(H2O)2) nanoparticles have been synthesized by a simple and rapid chemical precipitation method. Different copper-organic complexes were used to control the size and morphology of products. The morphology and structure of the as-synthesized products were
Mononuclear and dinuclear chiral vanadium (V) complexes with tridentate Schiff bases derived from< i> R</i>(-)-1, 2-diaminopropane: Synthesis, structure, characterization and catalytic properties.
Romanowski G and Wera M.
Polyhedron, 29(13), 2747-2754 (2010)
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