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About This Item
Linear Formula:
[(CH3)2CH]3C6H2SO2Cl
CAS Number:
Molecular Weight:
302.86
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
229-479-6
Beilstein/REAXYS Number:
1218575
MDL number:
Assay:
97%
Form:
solid
Quality Level
assay
97%
form
solid
mp
92-94 °C (lit.)
solubility
ethanol: soluble 5%, clear, colorless to light yellow
SMILES string
CC(C)c1cc(C(C)C)c(c(c1)C(C)C)S(Cl)(=O)=O
InChI
1S/C15H23ClO2S/c1-9(2)12-7-13(10(3)4)15(19(16,17)18)14(8-12)11(5)6/h7-11H,1-6H3
InChI key
JAPYIBBSTJFDAK-UHFFFAOYSA-N
Application
2,4,6-Triisopropylbenzenesulfonyl chloride can be used in the analysis of phosphonolipids in eggyolk by HPLC/MS technique.
It can also be used to synthesize:
It can also be used to synthesize:
- Dimeric neomycin-neomycin conjugate with a flexible linker, 2,2′-(ethylenedioxy)bis(ethylamine).
- Coupling reagents for the synthesis of oligonucleotides.
- Sulfonates of pyrimidine nucleosides. These sulfonates can be displaced by nucleophiles in the presence of palladium-catalysts.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Sunil Kumar et al.
Journal of the American Chemical Society, 133(19), 7361-7375 (2011-04-29)
A dimeric neomycin-neomycin conjugate 3 with a flexible linker, 2,2'-(ethylenedioxy)bis(ethylamine), has been synthesized and characterized. Dimer 3 can selectively bind to AT-rich DNA duplexes with high affinity. Biophysical studies have been performed between 3 and different nucleic acids with varying
A General Route to 4-C-Substituted Pyrimidine Nucleosides
Ulrich Hennecke,et al.
Synthesis, 6, 929-935 (2007)
Studies on Polynucleotides. LII. 1 The Use of 2, 4, 6-Triisopropylbenzenesulfonyl Chloride for the Synthesis of Internucleotide Bonds2.
Lohrmann R and Khorana HG.
Journal of the American Chemical Society, 88(4), 829-833 (1966)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 119490-100G | 04061838345318 |
| 119490-25G | 04061833544341 |
