120227
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
95%
Synonym(s):
Hantzsch ester
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About This Item
Empirical Formula (Hill Notation):
C13H19NO4
CAS Number:
Molecular Weight:
253.29
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
214-561-6
MDL number:
Product Name
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate, 95%
InChI key
LJXTYJXBORAIHX-UHFFFAOYSA-N
InChI
1S/C13H19NO4/c1-5-17-12(15)10-7-11(13(16)18-6-2)9(4)14-8(10)3/h14H,5-7H2,1-4H3
SMILES string
CCOC(=O)C1=C(C)NC(C)=C(C1)C(=O)OCC
assay
95%
form
solid
mp
178-183 °C (lit.)
solubility
organic solvents: soluble
functional group
ester
Quality Level
Related Categories
Application
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate (DTP) was used to study the mechanism of electrochemical oxidation of DTP in ethanol/water solutions on a glassy carbon electrode.
Used as a hydrogen source in organocatalytic reductive amination and conjugate reduction.
General description
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate is often used as a building block in organic synthesis for the preparation of various biologically active compounds.
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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V N Kovalenko et al.
Voprosy pitaniia, (2)(2), 44-49 (1982-03-01)
The efficacy of pharmacopeial alpha-tocopheryl acetate, alpha-tocopheronolactone and the antioxidant diludin was studied as to the possibilities of preventing E-hypovitaminosis muscle dystrophy in rabbits. alpha-Tocopheronolactone action was similar to that of pharmacopeial alpha-tocopheryl acetate as regards E-vitamin activity that was
G I Klebanov et al.
Biomeditsinskaia khimiia, 52(1), 69-82 (2006-06-03)
Antioxidant activity (AA) of inhibitors of free radical reactions (FRR) (dieton, mexidol, trypsin), aplied to the dressing material for wound healing was studied. In our work we used a model system containing suspension of laminated liposome, formed from fraction of
Seung Jun Hwang et al.
Scientific reports, 3, 1309-1309 (2013-02-20)
Core@shell electrocatalysts for fuel cells have the advantages of a high utilization of Pt and the modification of its electronic structures toward enhancement of the activities. In this study, we suggest both a theoretical background for the design of highly
N A Basova et al.
Rossiiskii fiziologicheskii zhurnal imeni I.M. Sechenova, 88(5), 650-657 (2002-07-26)
The main concern of this work was to examine the relation between altered antioxidant status on the one hand and increase in L-tryptophan absorption in the small intestine in order to bring further information regarding to possible role of vitamin
Jing Zhang et al.
iScience, 23(1), 100755-100755 (2019-12-31)
The alkoxyl radical is an essential reactive intermediate in mechanistic studies and organic synthesis with hydrogen atom transfer (HAT) reactivity. However, compared with intramolecular 1,5-HAT or intermolecular HAT of alkoxyl radicals, the intramolecular 1,2-HAT reactivity has been limited to theoretical
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