124664
4-Bromophenylacetonitrile
98%
Synonym(s):
4-Bromobenzyl cyanide
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About This Item
Linear Formula:
BrC6H4CH2CN
CAS Number:
Molecular Weight:
196.04
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
240-602-2
MDL number:
Assay:
98%
Form:
solid
InChI key
MFHFWRBXPQDZSA-UHFFFAOYSA-N
InChI
1S/C8H6BrN/c9-8-3-1-7(2-4-8)5-6-10/h1-4H,5H2
SMILES string
Brc1ccc(CC#N)cc1
assay
98%
form
solid
mp
47-49 °C (lit.)
functional group
bromo, nitrile
General description
4-Bromophenylacetonitrile undergoes reduction using 1,1,3,3-tetramethyldisiloxane activated by a non-toxic titanium(IV) isopropoxide to yield 4-bromophenylethylamine.
Application
4-Bromophenylacetonitrile has been used in the synthesis of :
- new fluorene-based alternating polymers
- light-emitting copolymer, poly(N 4,N 4-bis-(4-phenyl)-N 4,N 4′-bis-[4-(2-ethylhexyloxy)phenyl]-biphenyl-4,4′-diamine-co-1,2-bis(4′-phenyl)-1-(9′′,9′′-dihexyl-3-fluorenyl)ethane) using a Yamamoto coupling reaction
- N-methyl-3,4-bis(4-(N-(1-naphthyl)phenylamino)phenyl)maleimide, a novel non-doped red organic light-emitting diode (OLED) material
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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Hsiu-Chih Yeh et al.
Chemical communications (Cambridge, England), (20)(20), 2632-2633 (2003-11-05)
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A mild and efficient method for the reduction of nitriles.
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