125423
1,4-Cyclohexanedione
98%
Synonym(s):
1,4-Dioxocyclohexane, Cyclohexan-1,4-dione, Tetrahydroquinone
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About This Item
Linear Formula:
C6H8(=O)2
CAS Number:
Molecular Weight:
112.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-306-0
Beilstein/REAXYS Number:
774152
MDL number:
Assay:
98%
Form:
solid
Product Name
1,4-Cyclohexanedione, 98%
InChI key
DCZFGQYXRKMVFG-UHFFFAOYSA-N
InChI
1S/C6H8O2/c7-5-1-2-6(8)4-3-5/h1-4H2
SMILES string
O=C1CCC(=O)CC1
assay
98%
form
solid
mp
77-78.5 °C (lit.)
functional group
ketone
Quality Level
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Application
1,4-Cyclohexanedione has been used to study the influence of visible light on the bromate-1,4-cyclohexanedione-ferroin oscillating reaction.
General description
1,4-Cyclohexanedione(CHD) undergoes uncatalyzed oscillatory reactions during oxidation by acidic bromate in nitric acid and sulphuric acid solution. It reacts with acidic bromate to form 1,4-dihydroxybenzene which on further oxidation and bromination yields 1,4-benzoquinone and bromoorganics.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
269.6 °F - closed cup
flash_point_c
132 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Uncatalysed oscillatory chemical reactions. Oxidation of 1, 4-cyclohexanedione by bromate in sulfuric or nitric acid solution.
Farage VJ and Janjic D.
Chemical Physics Letters, 88(3), 301-304 (1982)
Photosensitive, bubble-free, bromate-1, 4-cyclohexanedione oscillating reactions. Illumination control of pattern formation.
Kurin-Csorgei K, et al.
The Journal of Physical Chemistry A, 101(37), 6827-6829 (1997)
The 1, 4-cyclohexanedione-bromate-acid oscillatory system. 3. Detailed mechanism.
Szalai I and Koros E.
The Journal of Physical Chemistry A, 102(35), 6892-6897 (1998)
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