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Merck
CN

125857

2,3-Diaminopyridine

95%

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About This Item

Empirical Formula (Hill Notation):
C5H7N3
CAS Number:
Molecular Weight:
109.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-200-9
Beilstein/REAXYS Number:
109869
MDL number:
Assay:
95%
Form:
powder
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Quality Level

assay

95%

form

powder

mp

110-115 °C (lit.)

solubility

H2O: soluble 50 mg/mL, opaque (brown to very dark brown)

SMILES string

Nc1cccnc1N

InChI

1S/C5H7N3/c6-4-2-1-3-8-5(4)7/h1-3H,6H2,(H2,7,8)

InChI key

ZZYXNRREDYWPLN-UHFFFAOYSA-N

General description

2,3-Diaminopyridine forms the bis-condensed Schiff base with salicylaldehyde. It forms charge transfer complex with tetrachloro-p-benzoquinone and tetracyanoethylene.

Application

2,3-Diaminopyridine was used in the synthesis of 2,3-diaminopyridinium-4-hydroxybenzoate. It was used as internal standard in analysis of poly(amidoamine)dendrimers having different terminal functionalities by capillary electrophoresis. It was used as reagent in synthesis of imidazopyridines and organometallic complexes.


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Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves



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Synthesis and anti-bacterial/catalytic properties of Schiff bases and Schiff base metal complexes derived from 2, 3-diaminopyridine.
Jeewoth T, et al.
Synth. React. Inorg. Met.-Org. Chem. , 30(6), 1023-1038 (2000)
Hoong-Kun Fun et al.
Acta crystallographica. Section E, Structure reports online, 65(Pt 7), o1496-o1497 (2009-01-01)
In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(3) (-), the pyridine N atom is protonated. In the 4-hydroxy-benzoate anion, the carboxyl-ate group is twisted slightly out of the benzene ring plane by an angle of 3.77 (5)°. The protonated N atom and one
W J Coates et al.
Journal of medicinal chemistry, 36(10), 1387-1392 (1993-05-14)
The synthesis and phosphodiesterase (PDE) inhibitory profile of a series of imidazopyridines, including sulmazole and isomazole, on separated PDE isoenzymes are described. The results show that both sulmazole and isomazole are weak inhibitors of PDE III, and their inotropic activity



Global Trade Item Number

SKUGTIN
125857-1G04061838723697
125857-5G04061838723710
125857-25G04061838723703