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Merck
CN

126373

3,4-Dimethylaniline

98%

Synonym(s):

3,4-Xylidine, 4-Amino-1,2-dimethylbenzene, 4-Amino-o-xylene

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About This Item

Linear Formula:
(CH3)2C6H3NH2
CAS Number:
95-64-7
Molecular Weight:
121.18
Beilstein:
507414
EC Number:
202-437-4
MDL number:
MFCD00007810
UNSPSC Code:
12352100
PubChem Substance ID:
24847724
NACRES:
NA.22

Key Documents

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Quality Level

100

Assay

98%

bp

226 °C (lit.)

mp

49-51 °C (lit.)

solubility

H2O: slightly soluble
alcohol: soluble

SMILES string

Cc1ccc(N)cc1C

InChI

1S/C8H11N/c1-6-3-4-8(9)5-7(6)2/h3-5H,9H2,1-2H3

InChI key

DOLQYFPDPKPQSS-UHFFFAOYSA-N

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Application

3,4-Dimethylaniline (3,4-DMA) has been used to study the electron donor-acceptor (EDA) interaction between 2,3-dicyano-1,4-naphthoquinone (DCNQ) and 3,4-dimethylaniline, in chloroform and dichloromethane. It can also be used for reactions with MoO(X)2(dtc)2 (X = Cl or Br; dtc = diethyldithiocarbamate) in methanol to form ionic imido complexes of the type [MoNAr(dtc)3]2[Mo6O19] or MoNAr(dtc)3]4[Mo8O26].

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

224.6 °F - closed cup

Flash Point(C)

107 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN6517
BCCJ9810
STBC2232V
STBB7653V
STBB7653

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Gururaj M Neelgund et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78(1), 480-487 (2010-12-15)
The electron donor-acceptor (EDA) interaction between 2,3-dicyano-1,4-naphthoquinone (DCNQ) and 3,4-dimethylaniline (3,4-DMA) is studied in chloroform, dichloromethane and 1:1 (v/v) mixture of chloroform and dichloromethane. The rate of formation of the product was measured as a function of time using UV-vis
Martin Minelli et al.
Inorganic chemistry, 41(23), 5954-5960 (2002-11-12)
Anilines with alkyl substituents on the phenyl ring (ArNH2 = 2,4,6-trimethylaniline; 2,3-, 2,4-, 2,6-, and 3,4-dimethylaniline; and 2,6-diisopropylaniline) react with MoO(X)2(dtc)2 (X = Cl or Br; dtc = diethyldithiocarbamate) in methanol in the presence of 2 equiv of triethylamine to
Akito Takeuchi et al.
Journal of occupational health, 53(3), 230-233 (2011-03-23)
The purpose of this research was to develop a determination method for xylidines (XLDs) in workplace air for risk assessment. The characteristics of the proposed method, such as recovery, detection limit, reproducibility, and storage stability of the samples were examined.
Robert J Strife et al.
Journal of chromatography. A, 1216(41), 6970-6973 (2009-09-08)
The assessment of human exposure to specific isomers of dimethylanilines (DMA's) is of interest for the evaluation of potential exposure-health outcome relationships. Improved analytical methods will help in identifying the environmental sources of such exposures. The separation of all six
Tetyana Kobets et al.
Mutation research, 844, 10-24 (2019-07-22)
DNA-damaging activities of twenty-four structurally diverse unsubstituted and substituted cyclic compounds were assessed in embryo-fetal chicken livers. Formation of DNA adducts and strand breaks were measured using the nucleotide 32P-postlabelling (NPL) and comet assays, respectively. Unsubstituted monocyclic benzene, polycyclic fused
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