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Merck
CN

129739

3-Methyl-2-benzothiazolinone hydrazone hydrochloride hydrate

97%

Synonym(s):

MBTH hydrochloride hydrate

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About This Item

Empirical Formula (Hill Notation):
C8H9N3S · HCl · xH2O
CAS Number:
Molecular Weight:
215.70 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
238-428-7
MDL number:
Assay:
97%
Form:
solid
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assay

97%

form

solid

InChI key

IYXXQOGEFHAQGU-GPWRMYTLSA-N

InChI

1S/C8H9N3S.ClH.H2O/c1-11-6-4-2-3-5-7(6)12-8(11)10-9;;/h2-5H,9H2,1H3;1H;1H2/b10-8-;;

SMILES string

Cl[H].[H]O[H].CN1\C(Sc2ccccc12)=N\N

mp

276-278 °C (dec.) (lit.)

Application

3-Methyl-2-benzothiazolinone hydrazone hydrochloride hydrate (MBTH hydrochloride hydrate) was used as an electrophilic coupling reagent for the determination of residual chlorine.
Chromogenic reagent for the determination of benzodiazepines, cholesterol, and enzyme activity. Used in the synthesis of benzothiazolium azo dyes.

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Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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J N Rodríguez-López et al.
Analytical biochemistry, 216(1), 205-212 (1994-01-01)
A continuous spectrophotometric method for the rapid determination of monophenolase activity of tyrosinase is described. This method is based on the coupling reaction between 3-methyl-2-benzothiazolinone hydrazone (MBTH) and the quinone products of the oxidation of various monophenols in the presence
Dyes and Pigments, 21, 159-159 (1993)
Indian J. Chem. B, 32, 44-44 (1993)
Bull. Soc. Chim. Belg., 102, 233-233 (1993)
Riyad Ahmed Al-Okab et al.
Journal of hazardous materials, 170(1), 292-297 (2009-05-30)
Novel, sensitive and rapid spectrophotometric methods, using phenoxazine (PNZ), 2-chlorophe-noxazine (CPN) and 2-trifluoromethylphenoxazine (TPN) as chromogenic reagents for the determination of residual chlorine are proposed. The methods are based on the reduction of chlorine by an electrophilic coupling reagent, 3-methyl-2-benzothiazoline

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