133299
Benzyl isocyanide
98%
Synonym(s):
(Isocyanomethyl)benzene, Benzyl isonitrile
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About This Item
Linear Formula:
C6H5CH2NC
CAS Number:
Molecular Weight:
117.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
233-738-9
MDL number:
Assay:
98%
Quality Level
assay
98%
refractive index
n20/D 1.521 (lit.)
bp
105-106 °C/75 mmHg (lit.)
density
0.962 g/mL at 25 °C (lit.)
functional group
amine, isonitrile, phenyl
storage temp.
−20°C
SMILES string
[C-]#[N+]Cc1ccccc1
InChI
1S/C8H7N/c1-9-7-8-5-3-2-4-6-8/h2-6H,7H2
InChI key
RIWNFZUWWRVGEU-UHFFFAOYSA-N
General description
Benzyl isocyanide forms phosphaalkene-containing complexes.
Application
Benzyl isocyanide was used in the synthesis of Ru(II) complexes containing hydrazine and benzyl isocyanide ligands. It was used in a three-component coupling process leading to O- and N-arylamides.
Other Notes
May darken in storage
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
174.2 °F - closed cup
flash_point_c
79 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Synthesis and X-ray studies of ruthenium (II) complexes containing hydrazine and benzyl isocyanide ligands.
Owalude SO, et al.
Bulletin of the Chemical Society of Ethiopia, 27(3), 405-411 (2013)
Samantha N MacMillan et al.
Chemical communications (Cambridge, England), (40)(40), 4172-4174 (2007-10-11)
Reaction of (N(3)N)ZrPHPh (N(3)N=N(CH(2)CH(2)NSiMe(3))(3)(3-)) with PhCH(2)N[triple bond]C affords the 1,1-insertion product (N(3)N)Zr[C(PHPh)=NCH(2)Ph], which thermally rearranges to the phosphaalkene-containing complex, (N(3)N)Zr[N(CH(2)Ph)C(H)=PPh].
Zeinab Faghih et al.
Iranian journal of pharmaceutical research : IJPR, 19(3), 134-143 (2021-03-09)
The complex [(PhCH2NC)AuCl], 1, was prepared by the reaction of [(Me2S)AuCl], A, with an equimolar amount of benzyl isocyanide (PhCH2NC) ligand. Through a salt metathesis reaction, the chloride ligand in 1 was replaced by potassium benzothiazole-2-thiolate (Kbt) and potassium benzoimidazole-2-thiolate
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 133299-5G | 04061838729422 |
| 133299-1G | 04061838729415 |