137685
2-Bromoethyl acetate
97%
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About This Item
Linear Formula:
CH3COOCH2CH2Br
CAS Number:
Molecular Weight:
167.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-159-8
Beilstein/REAXYS Number:
1743110
MDL number:
Assay:
97%
InChI
1S/C4H7BrO2/c1-4(6)7-3-2-5/h2-3H2,1H3
InChI key
RGHQKFQZGLKBCF-UHFFFAOYSA-N
SMILES string
CC(=O)OCCBr
assay
97%
impurities
<3% acetic anhydride
bp
159 °C (lit.)
mp
−14-−13.8 °C (lit.)
density
1.514 g/mL at 25 °C (lit.)
functional group
bromo, ester
Application
2-Bromoethyl acetate was used as alkylating reagent during asymmetric total synthesis of (+)-1-deoxylycorine and (+)-lycorine.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
159.8 °F - closed cup
flash_point_c
71 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Takuya Uto et al.
Physical chemistry chemical physics : PCCP, 20(31), 20669-20677 (2018-07-31)
Chitin is a promising biomass resource and has high potential for industrial applications owing to its huge annual production in nature. However, it exhibits poor processability and solubility due to its very stable and crystalline character. Recently, ionic liquids (ILs)
The first asymmetric total syntheses of (+)-lycorine and (+)-1-deoxylycorine.
Schultz AG, et al.
Journal of the American Chemical Society, 118(26), 6210-6219 (1996)
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