137685
2-Bromoethyl acetate
97%
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About This Item
Linear Formula:
CH3COOCH2CH2Br
CAS Number:
Molecular Weight:
167.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-159-8
Beilstein/REAXYS Number:
1743110
MDL number:
Assay:
97%
InChI
1S/C4H7BrO2/c1-4(6)7-3-2-5/h2-3H2,1H3
InChI key
RGHQKFQZGLKBCF-UHFFFAOYSA-N
SMILES string
CC(=O)OCCBr
assay
97%
impurities
<3% acetic anhydride
bp
159 °C (lit.)
mp
−14-−13.8 °C (lit.)
density
1.514 g/mL at 25 °C (lit.)
functional group
bromo, ester
Application
2-Bromoethyl acetate was used as alkylating reagent during asymmetric total synthesis of (+)-1-deoxylycorine and (+)-lycorine.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
159.8 °F - closed cup
flash_point_c
71 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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The first asymmetric total syntheses of (+)-lycorine and (+)-1-deoxylycorine.
Schultz AG, et al.
Journal of the American Chemical Society, 118(26), 6210-6219 (1996)
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