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137715

2,4,6-Tribromophenol

Name: 2,4,6-Tribromophenol
Brand: ALDRICH

99%

Synonym(s):

1,3,5-Tribromo-2-hydroxybenzene, Bromol

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About This Item

Linear Formula:

Br₃C₆H₂OH

CAS Number:

118-79-6

Molecular Weight:

330.80

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24848344

EC Number:

204-278-6

Beilstein/REAXYS Number:

776920

MDL number:

MFCD00002150

Assay:

99%

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Properties

vapor density

11.4 (vs air)

Quality Level

100

assay

99%

bp

282-290 °C/746 mmHg (lit.)

mp

90-94 °C (lit.)

solubility

water: soluble 0.007g/100ml at 25 °C, chloroform: soluble, diethyl ether: soluble, ethanol: soluble, methanol: soluble, methylene chloride: soluble

functional group

bromo

SMILES string

Oc1c(Br)cc(Br)cc1Br

InChI

1S/C6H3Br3O/c7-3-1-4(8)6(10)5(9)2-3/h1-2,10H

InChI key

BSWWXRFVMJHFBN-UHFFFAOYSA-N

Description

General description

2,4,6-Tribromophenol undergoes oxidative degradation catalyzed by SiO₂-supported iron(III)-5,10,15,20-tetrakis(4-carboxyphenyl) porphyrin. It is degraded by Bacillus sp.GZT strain via reductive bromination as major degradation pathway. It is a widely used brominated flame retardant.

Application

2,4,6-Tribromophenol was used in analysis of nonylphenol, nonylphenol monoethoxylate and octylphenol in sediment, water and fish tissue.

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pictograms

GHS07,GHS09

signalword

Warning

hcodes

H317,H319,H400

pcodes

P261 - P264 - P273 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Aquatic Acute 1 - Eye Irrit. 2 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Potassium monopersulfate oxidation of 2,4,6-tribromophenol catalyzed by a SiO2-supported iron(III)-5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin.

Qianqian Zhu et al.

Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering, 48(13), 1593-1601 (2013-08-21)

Iron(III)-porphyrin complexes are generally regarded as green catalysts, since they mimic the catalytic center of cytochrome-P450 and widely used as green catalysts for degrading halogenated phenols in wastewater, such as landfill leachates. However, iron(III)-porphyrins are deactivated by self-oxidation in the

Estrogenic alkylphenols in fish tissues, sediments, and waters from the UK Tyne and Tees estuaries.

Lye CM, et al.

Environmental Science & Technology, 33(7), 1009-1014 (1999)

Optimisation of a dispersive liquid-liquid microextraction method for the simultaneous determination of halophenols and haloanisoles in wines.

C Pizarro et al.

Journal of chromatography. A, 1217(49), 7630-7637 (2010-11-03)

A dispersive liquid-liquid microextraction (DLLME) method has been optimised for simultaneously extracting 2,4,6-trichloranisole (TCA), 2,3,4,6-tetrachloroanisole (TeCA), 2,4,6-tribromoanisole (TBA), pentachloroanisole (PCA), 2,4,6-trichlorophenol (TCP), 2,3,4,6-tetrachlorophenol (TeCP), 2,4,6-tribromophenol (TBP) and pentachlorophenol (PCP) from wine. The haloanisoles and halophenols were automatically determined using a

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Global Trade Item Number

SKU	GTIN
137715-100G	04061838731975
137715-5G	04061838731982