138029
Furil
98%
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About This Item
Empirical Formula (Hill Notation):
C10H6O4
CAS Number:
Molecular Weight:
190.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
207-766-7
MDL number:
Product Name
Furil, 98%
InChI key
SXPUVBFQXJHYNS-UHFFFAOYSA-N
InChI
1S/C10H6O4/c11-9(7-3-1-5-13-7)10(12)8-4-2-6-14-8/h1-6H
SMILES string
O=C(C(=O)c1ccco1)c2ccco2
assay
98%
form
solid
mp
163-165 °C (lit.)
Gene Information
human ... ACHE(43), BCHE(590), CES1(1066)
Application
Furil was used in preparation of dioxomolybdenum(VI) complexes in situ.
General description
Furil undergoes catalytic asymmetric transfer hydrogenation to yield hydrofuroin.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Anzhelika Kabro et al.
Organic letters, 14(15), 4014-4017 (2012-07-27)
Catalytic asymmetric transfer hydrogenation of rac-furoin and furil produces hydrofuroin with up to 99% ee and 9:1 dr. This reaction provides an exceptionally easy access to optically active hydrofuroins in two straightforward steps from biomass-derived furfural (global production 200,000-300,000 t
Syntheses and spectroscopic studies on macrocyclic complexes of dioxomolybdenum (VI) with furil as precursor.
Rao DP, et al.
E-Journal of Chemistry, 9(2), 497-503 (2012)
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