138029
Furil
98%
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About This Item
Empirical Formula (Hill Notation):
C10H6O4
CAS Number:
Molecular Weight:
190.15
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
98%
form
solid
mp
163-165 °C (lit.)
SMILES string
O=C(C(=O)c1ccco1)c2ccco2
InChI
1S/C10H6O4/c11-9(7-3-1-5-13-7)10(12)8-4-2-6-14-8/h1-6H
InChI key
SXPUVBFQXJHYNS-UHFFFAOYSA-N
Gene Information
human ... ACHE(43), BCHE(590), CES1(1066)
General description
Furil undergoes catalytic asymmetric transfer hydrogenation to yield hydrofuroin.
Application
Furil was used in preparation of dioxomolybdenum(VI) complexes in situ.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Syntheses and spectroscopic studies on macrocyclic complexes of dioxomolybdenum (VI) with furil as precursor.
Rao DP, et al.
E-Journal of Chemistry, 9(2), 497-503 (2012)
Anzhelika Kabro et al.
Organic letters, 14(15), 4014-4017 (2012-07-27)
Catalytic asymmetric transfer hydrogenation of rac-furoin and furil produces hydrofuroin with up to 99% ee and 9:1 dr. This reaction provides an exceptionally easy access to optically active hydrofuroins in two straightforward steps from biomass-derived furfural (global production 200,000-300,000 t
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