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138274

2-Methoxyfuran

Name: 2-Methoxyfuran
Brand: ALDRICH

97%

Synonym(s):

2-Furyl methyl ether

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About This Item

Empirical Formula (Hill Notation):

C₅H₆O₂

CAS Number:

25414-22-6

Molecular Weight:

98.10

NACRES:

NA.22

PubChem Substance ID:

24848241

UNSPSC Code:

12352100

EC Number:

246-953-8

MDL number:

MFCD00003227

Assay:

97%

Form:

liquid

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Properties

Quality Level

100

assay

97%

form

liquid

refractive index

n20/D 1.447 (lit.)

density

1.065 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

COc1ccco1

InChI

1S/C5H6O2/c1-6-5-3-2-4-7-5/h2-4H,1H3

InChI key

OXCGHDNCMSOEBZ-UHFFFAOYSA-N

Description

General description

2-Methoxyfuran forms cycloadducts with maleic anhydride and N-methylmaleimide. It undergoes Friedel-Crafts reaction with nitroalkenes catalyzed by diphenylamine-tethered bis(oxazoline)-Zn(OTf)₂complexes.

Application

2-Methoxyfuran was used to study the hydrolysis of furan derivative by acid catalysis.

pictograms

GHS02

signalword

Danger

hcodes

H225

pcodes

P210

Hazard Classifications

Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

50.0 °F - closed cup

flash_point_c

10 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Asymmetric Friedel-Crafts alkylation of methoxyfuran with nitroalkenes catalyzed by diphenylamine-tethered bis(oxazoline)-Zn(II) complexes.

Han Liu et al.

Organic letters, 9(23), 4725-4728 (2007-10-11)

The first catalytic asymmetric Friedel-Crafts reaction of 2-methoxyfuran with nitroalkenes was developed under the catalysis of diphenylamine-tethered bis(oxazoline)-Zn(OTf)2 complexes. The reaction conditions and ligands were optimized, and the scope of the reaction was tested by varying the nitroalkenes. For most

General Acid Catalysis in the Hydrolysis of a Furan Derivative.

KANKAANPERA A and AALTONEN R.

Acta Chemica Scandinavica, 26(6), 2537- 2540 (1972)

Structural studies on cycloadducts of furan, 2-methoxyfuran, and 5-trimethylsilylcyclopentadiene with maleic anhydride and N-methylmaleimide.

Yit Wooi Goh et al.

The Journal of organic chemistry, 73(1), 151-156 (2007-12-12)

The early stages of the retro-Diels-Alder reaction are clearly apparent in the structures of the cycloadducts formed between furan or 5-trimethylsilylcyclopentadiene with maleic anhydride and N-methylmaleimide. The degree of lengthening of the C-C bonds that break in this reaction is

Global Trade Item Number

SKU	GTIN
138274-5G	04061838732309