139076
5-Bromo-4-chloroindoxyl 1,3-diacetate
98%
Synonym(s):
5-Bromo-4-chloro-3-indolyl 1,3-diacetate
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About This Item
Empirical Formula (Hill Notation):
C12H9BrClNO3
CAS Number:
Molecular Weight:
330.56
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-200-6
Beilstein/REAXYS Number:
270885
MDL number:
Assay:
98%
InChI key
DSHQTSIXXYZXGR-UHFFFAOYSA-N
InChI
1S/C12H9BrClNO3/c1-6(16)15-5-10(18-7(2)17)11-9(15)4-3-8(13)12(11)14/h3-5H,1-2H3
SMILES string
CC(=O)Oc1cn(C(C)=O)c2ccc(Br)c(Cl)c12
assay
98%
mp
165-168 °C (lit.)
solubility
chloroform: soluble 50 mg/mL, clear, pale yellow to yellow
storage temp.
2-8°C
Application
5-Bromo-4-chloroindoxyl 1,3-diacetate was used as starting reagent in the synthesis of 5,5′-dibromo-4,4′-dichloroindigo.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Faten Arab-Jaziri et al.
New biotechnology, 30(5), 536-544 (2013-05-01)
Directed evolution was applied to the α-l-arabinofuranosidase from Thermobacillus xylanilyticus to confer better transglycosylation ability, particularly for the synthesis of benzyl α-l-arabinofuranosyl-(1,2)-α-d-xylopyranoside, starting from p-nitrophenyl α-l-arabinofuranoside (donor) and benzyl α-d-xylopyranoside (acceptor). The aim was to obtain mutants displaying both lower
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